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Chemistry World June 24, 2010 Phillip Broadwith	Aryl rings get a fluorine fix A mild and effective method for coupling trifluoromethyl groups on to aryl rings has been developed by US chemists.
Chemistry World March 19, 2009 Manisha Lalloo	Copper catalysts give meta aromatics UK Researchers have discovered that, simply by using a copper catalyst, they are able to perform tricky substitution reactions at a difficult position on benzene rings
Chemistry World October 9, 2014 Katrina Kramer	Largest Mobius molecule synthesized Researchers from Korea and Japan have put a new twist on aromaticity, synthesizing the largest Mobius aromatic molecule to date.
Chemistry World October 15, 2012 Simon Hadlington	ExBox snares polycyclic aromatic hydrocarbons US chemists have designed a novel macrocyclic molecule that may be able to scavenge an important class of toxic hydrocarbons from the environment.
Chemistry World June 23, 2011 Simon Hadlington	Breaking the carbon-fluorine bond US chemists have discovered a new way to break the bond between carbon and fluorine atoms - the strongest carbon bond there is.
Chemistry World December 20, 2007 Richard Van Noorden	Off-the-Peg Organic Synthesis Goes Commercial Chemists have created an efficient way to make small molecules by repeatedly using just one coupling reaction to clip together pre-prepared chemical fragments is going commercial.
Chemistry World February 8, 2006 Jon Evans	To Boldly go Where no Chemist Has Gone Before Studying the interactions between different molecular fragments is taking researchers to the uncharted regions of chemical space.
Chemistry World September 18, 2015 Tim Wogan	Shining a light on amine synthesis A new method for site selective amination of aromatic organic compounds has been developed by researchers in the US.
Chemistry World May 16, 2010 Simon Hadlington	Anions enjoy a taste of pi European researchers have captured the moment when an anion interacts with the pi electron cloud of an aromatic molecule, something that has been known to occur but never seen at work.
Chemistry World November 3, 2008 Simon Hadlington	Organic synthesis set for auto-pilot Peptides are routinely made by machines that couple together amino acid components. Could organic synthesis ever get this simple?
Chemistry World September 20, 2007 Lewis Brindley	New Catalyst Rings the Changes Organic chemists in the US have developed a method to control the stereochemistry of a useful intramolecular Diels-Alder reaction.
Chemistry World January 27, 2010 Phillip Broadwith	Cracking carbon-carbon bonds Chemists in the US have discovered a tungsten complex that can break a strong carbon-carbon bond in an aromatic ring.
Chemistry World June 21, 2012 Phillip Broadwith	Building nanographene by organic synthesis Japanese scientists are making tiny fragments of graphene using direct cross-coupling of C-H bonds to determine what effect size and edge geometry have on the properties of carbon materials.
Chemistry World April 14, 2009 Lewis Brindley	Osmium and pyridine ring together Organic chemists in China have found a way to put osmium into a pyridine ring - leading to the synthesis of the first metallapyridinium complex.
Chemistry World July 9, 2012 Phillip Broadwith	'Molecular cobra' turns C-H to C=C A reagent developed by US chemists can selectively introduce synthetically useful C=C double bonds into unactivated carbon chains, guided by an activating group attached to a nearby oxygen or nitrogen atom.
Chemistry World May 24, 2007 James Mitchell Crow	Palladium Coupling in Fewer Steps Look out Suzuki - Canadian chemists have successfully joined up simple benzene ring-like aromatics without any pre-activation.
Chemistry World March 21, 2007 Richard Van Noorden	Forcing a Reaction US chemists have forced molecules to react by ripping their bonds apart with ultrasound. The scientists carefully stretched one targeted bond until it snapped, guiding the molecule's subsequent reaction into pathways forbidden by conventional chemistry.
Chemistry World September 9, 2009 Lewis Brindley	Daisy-chain polymers bring artificial muscles a step closer American chemists have made molecular 'daisy-chains' containing threaded rings that can be pulled taut or slackened by chemical stimuli.
Chemistry World April 15, 2010 Simon Hadlington	Lead joins the aromatic ring club Scientists in Japan have successfully incorporated an atom of lead into an aromatic molecule - the heaviest metal so far to be 'aromatised'.
Chemistry World August 17, 2009 James Urquhart	New method for fluorinating compounds Fluorine atoms are incorporated into aromatic organic compounds for many reasons, including their ability to increase metabolic stability, solubility and bioavailability.
Chemistry World June 8, 2014 David Bradley	Carbon--carbon couplings go 3D Chemists have devised a new stereospecific coupling reaction for electron-rich aromatics using secondary and tertiary boronic esters that works under mild conditions.
Chemistry World July 16, 2009 Simon Hadlington	Strange vibrations Researchers in Taiwan have shown that in a relatively simple molecular system the induced vibrations can inhibit the breaking of the bond and slow the reaction down.
Technology Research News August 13, 2003	Molecule makes ring rotor Researchers from the University of Edinburgh in Scotland have interlocked large, ring-shaped molecules to make a molecular rotor that moves in only one direction. The molecule could eventually be used as a nanoscale motor or winch.
Chemistry World January 29, 2010 Phillip Broadwith	Silicon goes aromatic Chemists in the UK have constructed a structural analogue of benzene made from silicon atoms. The molecule is not flat like benzene, but it reveals a new type of aromatic stabilisation.
Chemistry World November 27, 2009 Simon Hadlington	A simple way to join an olefin to an arene Chemists in the US have developed a simple and effective way to carry out a key class of reaction in organic synthesis - the bolting an olefin to an aromatic ring.
Chemistry World March 31, 2009 Lewis Brindley	Giving molecules a stretch A simple way to stretch small molecules and measure the forces at play has been developed by researchers in the US.
Chemistry World December 19, 2010 Simon Hadlington	Novel route to key aromatics US chemists have found a new way to create aromatic compounds from straight chains of hydrocarbons by using an iridium-based catalyst.
Chemistry World November 3, 2011 David Bradley	Faster Synthesis of Fluorine Radioisotope Imaging Agents A palladium-containing fluorination reagent can be used to quickly synthesise aromatic molecules labelled with fluorine-18, a positron emitter used in molecular imaging.
Chemistry World March 6, 2015 James Morey	Catalytic arylation methods: from the academic lab to industrial processes What if you wanted to arylate a sulfur atom instead of a carbon? Or build up the aryl group from scratch? I suggest turning to Catalytic arylation methods as your first port of call.
Chemistry World November 2010	Carbon Couplers Take the Prize Three giants of organic chemistry, who pioneered palladium-catalysed cross coupling reactions, have shared this year's Nobel prize.
Chemistry World November 11, 2012 Simon Hadlington	'Nano-welding' taken to the limits as specific bonds are cut and formed In a remarkable demonstration of the extreme limits of nanoscale engineering, researchers from the US and China have used the tip of a scanning tunnelling microscope to cleave and form selected chemical bonds on a complex molecule.
Chemistry World January 28, 2015	Rubriflordilactone A It's likely that organic chemists have been practicing retrosynthesis in one form or another for at least a century, and certainly for decades before E J Corey formalized the concept in the mid-1990s
Chemistry World September 25, 2012 Ian LeGuillou	Flattening the buckybowl The dome-like structure of corannulene has been flattened by adding an unprecedented 10 phenyl rings to its rim. Corannulene is essentially a slice off the top of a buckyball, with five six-membered aromatic rings fused together.
Chemistry World February 2011 Paul Docherty	Column: Totally Synthetic Although most of the natural products I've discussed have had biological activity at the core of the rationale for their synthesis, most organic chemists will admit that an unusual chemical structure is by far the stronger draw.
Chemistry World September 29, 2015	Navigating chemical space How big is chemistry? I don't mean how important is it, or how many people do it, but rather, how many molecules are there that we could make?
Chemistry World July 1, 2012 Paul Docherty	Vincorine Cage-structured natural products are some of the most appealing (if perhaps not appetising) targets for organic chemists -- perhaps due to their obvious intricacy of form, but also because of their structural rigidity.
Reactive Reports Issue 63 David Bradley	Chemists Go Round the Bend Chemists often think of molecular wires as "shape-persistent" rods with limited flexibility, but researchers have now shown that molecular wires can be bent into ring shapes.
Chemistry World April 15, 2009 Phillip Broadwith	Heteroaromatic rings of the future UK scientists have created a computer program to work out all the aromatic heterocycles that could be synthesised, hoping to expand the range of molecules used in the pharmaceutical and other industries.
Chemistry World May 28, 2015 Matthew Gunther	Purely inorganic aromatic ion synthesized Scientists in the US have successfully synthesized an aromatic ion made from only nitrogen and phosphorus. The anion is a rare example of a stable aromatic species containing no carbon atoms.
Chemistry World March 2011 Paul Docherty	Column: Totally Synthetic Discovered independently by two chemists in the 1870s, it's remarkable that 140 years later, science is still tweaking and improving the aldol reaction.
Chemistry World November 2, 2015	Batzelladine B Of all the diverse substances that nature produces, the alkaloids -- small molecules containing basic nitrogen -- have had the greatest impact on human history and health.
Chemistry World April 4, 2013 Phillip Broadwith	A solution to fluoronium riddle The first evidence for hypervalent fluorine cations, or fluoronium ions, in solution has been found by US chemists.
Chemistry World August 2008	Column: In the pipeline Problems develop when there are too few workhorse reactions, which may well generate compounds that are too similar to each other. Are we at that stage now?
Chemistry World February 19, 2010 Simon Hadlington	Forcing stereoselectivity on reactive cations Chemists in the US have devised a dual catalyst strategy to tame the highly reactive iminium ion to give a high degree of stereochemical control over subsequent reactions of the ion.
Chemistry World September 28, 2015 Karl Collins	A witches' brew for trifluoromethylation Trifluoromethylating phenols is one example of a reaction that would be incredibly useful when attempting to tune the chemical and biological properties of molecules for pharmaceutical and agrochemical research.
Wired Erin Biba	Molecular Frameworks, the Building Blocks of All Life The world is complicated, but not as complicated as you might think. Most organic molecules derive from a few relatively simple architectures.
Chemistry World April 12, 2012 Simon Hadlington	Recruiting electrophiles for organic cross-coupling Chemists in the US have taken an unconventional approach to carbon cross-coupling and in doing so have potentially opened the door to the rapid and efficient synthesis of a wide range of organic compounds.
Chemistry World May 21, 2015 Simon Hadlington	Molecular pump points way to non-equilibrium chemistry Researchers in the US have developed an artificial molecular pump which can accumulate small, highly charged molecules against a concentration gradient.
Chemistry World April 21, 2011 James Urquhart	Lignin cut down to size by nickel catalyst A nickel-based homogeneous catalyst that breaks down lignin - the tough polymer that forms plant cell walls - into useful building blocks suitable for chemicals, including green fuels, has been developed by US scientists.
Chemistry World November 1, 2012 Laura Howes	Shining new light on the Ullmann reaction Ullmann C -- N coupling -- a copper mediated carbon -- nitrogen coupling reaction used to create arylamines -- is one of the most widely used reactions in the pharmaceutical industry.