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Chemistry World March 1, 2012 David Bradley	Roaming reactions double up in atmospheric chemistry Chemists have found a chemical reaction that ignores its reaction coordinate and seemingly bypasses the conventional mechanics of transition state theory to display two distinct 'roaming' mechanisms.
Chemistry World September 12, 2010 Simon Hadlington	Isotope effect seen on single molecule The isotope effect - where the rate of a reaction is altered depending on the presence of a given isotopic atom in the reactant - is a key tool for elucidating reaction mechanisms
Chemistry World June 23, 2015 Philip Ball	Ultra-bright x-rays film molecular reaction A team working at the Stanford Linear Collider in California claims to have made 'the first molecular movie' using ultra-fast x-ray scattering from molecules as they undergo a chemical reaction.
Chemistry World February 22, 2008 James Mitchell Crow	Rhodium Fast Tracks Route to Lactones Chemists in Canada have developed an efficient new way to make lactones, chemical components of many natural products and drugs.
Chemistry World June 23, 2011 Simon Hadlington	Breaking the carbon-fluorine bond US chemists have discovered a new way to break the bond between carbon and fluorine atoms - the strongest carbon bond there is.
Chemistry World December 3, 2009 Simon Hadlington	C-H Bond Activation Takes the Relaxing Route Chemists have uncovered a key factor that helps determine the reactivity of a C-H bond to oxidation.
Chemistry World November 13, 2008 Hayley Birch	Reactions Studied by Stop Motion Japanese and Israeli scientists have developed a technique that can track whole-molecule changes that occur during extremely rapid reactions.
Chemistry World October 12, 2006 Richard Van Noorden	Lasers on the Energy Ski Slope Researchers have shown that intense laser-light pulses can act as catalysts, controlling the end products of a chemical reaction without themselves being absorbed.
Chemistry World March 21, 2007 Richard Van Noorden	Forcing a Reaction US chemists have forced molecules to react by ripping their bonds apart with ultrasound. The scientists carefully stretched one targeted bond until it snapped, guiding the molecule's subsequent reaction into pathways forbidden by conventional chemistry.
Chemistry World May 21, 2010 Simon Hadlington	H-bond partner-swapping seen in the flesh The dance moves that a water molecule makes as it flips hydrogen bonds from one partner to another have been captured by US researchers.
Chemistry World November 11, 2009 James Urquhart	Structural snapshots of complex molecules US researchers have pioneered a new spectroscopy technique to uncover the precise sequence of atomic movements and structural changes that occur during complex chemical transformations.
Chemistry World July 15, 2010 Simon Hadlington	Synthetic enzyme catalyses Diels-Alder reaction The reaction is key to many organic syntheses and suggests that artificial enzymes could soon become part of the synthetic chemist's toolkit.
Chemistry World March 14, 2012 James Urquhart	Catalysis at the flick of a switch German researchers have created a molecular nanoswitch that can be reversibly and repeatedly turned on and off to control a chemical reaction.
Chemistry World January 27, 2010 Phillip Broadwith	Cracking carbon-carbon bonds Chemists in the US have discovered a tungsten complex that can break a strong carbon-carbon bond in an aromatic ring.
Chemistry World June 23, 2015 Matthew Gunther	Photo-catalysts shine light on chemical bond making A team of scientists from Israel and Germany have manipulated bond formation in a chemical reaction using high power lasers
Chemistry World June 13, 2012 Simon Hadlington	Exploding molecule provides 3D bond images Researchers from the US and Germany have demonstrated a new way to obtain accurate three-dimensional images of molecules, with precise measurements of the geometry of the molecule's chemical bonds.
Chemistry World December 9, 2013 Jessica Cocker	Hydrogen breaks strong bonds with brute force A method developed by Leo Lau of Western University in Canada and colleagues can break C -- H bonds without damaging the rest of the molecule.
Chemistry World February 27, 2011 Manisha Lalloo	Catalyst cleans up C-C bond formation Researchers in the US have developed an iridium catalyst that promotes carbon-carbon bond formation between methanol and allenes.
Chemistry World February 20, 2012 James Urquhart	Unusual kinetics of catalyst revealed US researchers have elucidated the unusual reaction kinetics of C-H activation by the palladium(II) catalyst (Pd(OAc) 2).
Chemistry World May 13, 2014 Jennifer Newton	Blurred bonds rationalized by heavy atom tunnelling A new theoretical study of anti-aromatic systems has attributed the unusual way that their I -bonds shift to quantum tunnelling.
Chemistry World July 29, 2010 Carol Stanier	Methane all lined up Swiss researchers have found that the way methane molecules vibrate when they hit a nickel surface can have a huge effect on their reactivity.
Chemistry World December 2, 2008 James Mitchell Crow	Just add air for cleaner carbon bonding UK scientists have found a new way to clip together organic molecules that could be the ultimate green approach to making carbon-carbon bonds
Chemistry World December 16, 2011 Kate McAlpine	Radical experiment assesses interstellar nitrogen Radical reactions are challenging to measure at cold temperatures, but an international team of researchers have recently clocked the rate for atomic nitrogen and hydroxyl radicals at 56K.
Chemistry World September 24, 2014 Richard Massey	Acetaldehyde photolysis: right to roam Australian and US chemists have re-shaped our understanding of an important photochemical reaction that defies classical transition state theory and proceeds via multiple barrierless 'roaming' pathways.
Chemistry World November 15, 2011 Kate McAlpine	Shedding light on ultracold reactions in space Two teams of researchers in the US and Europe have shown that light can play a bigger role than expected in the nascent field of ultracold atom-ion interactions.
Chemistry World May 13, 2013 Philip Ball	The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded?
Chemistry World January 29, 2015 Santiago Alvarez	What we mean when we talk about bonds The chemical bond is still a matter of lively debate among chemists, even a century after Gilbert Lewis introduced his electron pair bonding concept.
Chemistry World June 2, 2011 James Urquhart	Methane activation by organometallic reagent US scientists have demonstrated for the first time that a metal-carbon multiple bond complex can activate methane.
Chemistry World September 12, 2013 Andy Extance	Sulfur difluoride dimer exposes bonding strangeness Calculations on unusual bonding in the sulfur difluoride dimer FSSF 3 have provided evidence to help explain why some compounds don't follow long-established chemical rules.
Chemistry World January 6, 2010 Phillip Broadwith	Enzymes do the twist The way enzyme catalysts bind molecules to speed up their reactions is not as simple as once thought, say chemists from the UK and Spain.
Chemistry World November 1, 2007 Richard Van Noorden	Step Change for Organic Synthesis US chemists discovered how to attack a complex molecule's unreactive carbon-hydrogen bonds, without resorting to wasteful synthetic aids like protecting and directing groups.
Chemistry World March 3, 2014 David Bradley	Mechanical stress pulls cyclization into shape Researchers at the Ruhr University Bochum, in Germany, have calculated that enediyne toxins, compounds used as anticancer drugs, might undergo Bergman cyclization when put under stress.
Chemistry World April 28, 2011 Simon Hadlington	New method for aromatic coupling Chemists in Switzerland have developed a way to couple aromatic rings through the Friedel-Crafts mechanism - something many people would have believed impossible.
Chemistry World January 3, 2008 Simon Hadlington	Key Plank of Theoretical Chemistry Rescued Theoretical chemists can breathe a sigh of relief after the publication of a study which shows that a cornerstone of their discipline seems to be intact despite earlier evidence to the contrary.
Chemistry World September 26, 2013 Akshat Rathi	First pictures of hydrogen bonds unveiled Researchers in China report the first visualization of a hydrogen bond using atomic force microscopy.
Chemistry World April 14, 2006 Simon Hadlington	Deciphering Hydrogen Tunnelling in Enzymes Researchers have thrown important new light on the phenomenon of hydrogen tunnelling in biological catalysts. The finding is likely to spark a debate among biochemists about the fundamental nature of enzymes.
Chemistry World January 27, 2011 Laura Howes	Muons take kinetic isotope effects to extremes Scientists have used muons, elementary particles similar to electrons, to investigate the effect of isotope identity on one of the most fundamental reactions in chemistry.
Chemistry World August 30, 2009 Phillip Broadwith	C-H oxidation proves its worth US researchers are going against the grain of total synthesis and developing new approaches to complex molecules.
Chemistry World December 12, 2010 Andy Extance	Images show atom 'spinning top' control This is the first-ever imaging of an atomic angular momentum vector precessing in a magnetic field, a motion analogous to a spinning top spiralling about Earth's gravitational field as it slows.
Chemistry World October 22, 2014 Simon Hadlington	Isotope effect produces new type of chemical bond New work by researchers shows how substituting isotopes can result in fundamental changes in the nature of chemical bonding.
Chemistry World January 20, 2010 James Urquhart	Disilicate synthesis success A compound containing a stable silicon-silicon bond between two negatively charged pentacoordinated silicon atoms - silicates - has been synthesized and isolated for the first time by Japanese researchers.
Chemistry World December 21, 2009 Simon Hadlington	'Two-legged' molecular walker takes a stroll UK chemists have designed a two-legged molecule that can walk up and down a straight molecular track. The system could form the basis for artificial linear molecular motors that can transport cargoes in a way similar to molecular machines used in nature.
Chemistry World October 13, 2011 Phillip Broadwith	Following Electrons' Chemical Reaction Quickstep The oscillating electronic states of molecules nearby and passing through a conical intersection can now be probed directly.
Chemistry World March 9, 2006 Katharine Sanderson	Covalent Bonds Crack Under the Strain Chemists must consider engineering principles when designing molecules following news that tough carbon-to-carbon bonds break easily under mechanical strain.
Technology Research News October 20, 2004	Molecules positioned on silicon Dubbed multi-step feedback control lithography, this new fabrication process could eventually be used to construct prototype molecular electronic devices for future technologies in areas like consumer electronics and biomedical diagnostics.
Chemistry World November 2010 Paul Docherty	Column: Totally Synthetic Perhaps the most familiar (and dull - they do say that familiarity breeds contempt.) chemical reaction to medicinal chemists is the amide bond formation.
Chemistry World January 12, 2014 Andy Extance	Rocket reactor forces space hydrogen rethink Scientists have pushed low-temperature experimentation and computational chemistry to their limits to better understand hydrogen fluoride, which astronomers use to study regions of space that are otherwise hard to image.
Reactive Reports Issue 60 David Bradley	Mark Leach Interview with the owner of Meta-Synthesis, a company aimed to reveal the inner secrets of chemistry to as wide an audience as possible.
Chemistry World August 21, 2012 James Mitchell Crow	Watching single nanoparticles work By shining laser light on the modified tip of an atomic force microscope), researchers in Germany and the Netherlands have been able to watch a catalytic reaction in real time, zoomed right in to the nanoscale.
Chemistry World September 24, 2009 Phillip Broadwith	Carbon can't but tin can US chemists have discovered that distannynes - tin-based analogues of acetylenes - can react reversibly with ethene to make cyclic complexes.