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Chemistry World
March 9, 2006
Katharine Sanderson
Covalent Bonds Crack Under the Strain Chemists must consider engineering principles when designing molecules following news that tough carbon-to-carbon bonds break easily under mechanical strain. mark for My Articles similar articles
Chemistry World
September 15, 2011
David Bradley
Sound Approach to Unclicking Click Chemistry Ultrasound can be used to physically release a triazole from a polymer-companies. mark for My Articles similar articles
Chemistry World
March 31, 2009
Lewis Brindley
Giving molecules a stretch A simple way to stretch small molecules and measure the forces at play has been developed by researchers in the US. mark for My Articles similar articles
Chemistry World
March 3, 2014
David Bradley
Mechanical stress pulls cyclization into shape Researchers at the Ruhr University Bochum, in Germany, have calculated that enediyne toxins, compounds used as anticancer drugs, might undergo Bergman cyclization when put under stress. mark for My Articles similar articles
Chemistry World
October 12, 2006
Richard Van Noorden
Lasers on the Energy Ski Slope Researchers have shown that intense laser-light pulses can act as catalysts, controlling the end products of a chemical reaction without themselves being absorbed. mark for My Articles similar articles
Chemistry World
January 27, 2010
Phillip Broadwith
Cracking carbon-carbon bonds Chemists in the US have discovered a tungsten complex that can break a strong carbon-carbon bond in an aromatic ring. mark for My Articles similar articles
Chemistry World
July 16, 2009
Simon Hadlington
Strange vibrations Researchers in Taiwan have shown that in a relatively simple molecular system the induced vibrations can inhibit the breaking of the bond and slow the reaction down. mark for My Articles similar articles
Chemistry World
June 13, 2012
Simon Hadlington
Exploding molecule provides 3D bond images Researchers from the US and Germany have demonstrated a new way to obtain accurate three-dimensional images of molecules, with precise measurements of the geometry of the molecule's chemical bonds. mark for My Articles similar articles
Chemistry World
September 9, 2009
Lewis Brindley
Daisy-chain polymers bring artificial muscles a step closer American chemists have made molecular 'daisy-chains' containing threaded rings that can be pulled taut or slackened by chemical stimuli. mark for My Articles similar articles
Chemistry World
April 6, 2009
Nina Notman
Torn catalysts help polymers heal themselves Catalysts that are activated by a mechanical force tearing them in two have been designed by Dutch scientists. mark for My Articles similar articles
Chemistry World
March 8, 2009
Nina Notman
Polymer Crossroads Act as Tiny Reactors Scientists in the US have taken inspiration from a Dutch painter to create ultrasmall chemical reactors at the junctions of overlapping polymer nanofibres mark for My Articles similar articles
Chemistry World
November 13, 2008
Hayley Birch
Reactions Studied by Stop Motion Japanese and Israeli scientists have developed a technique that can track whole-molecule changes that occur during extremely rapid reactions. mark for My Articles similar articles
Chemistry World
January 19, 2010
Simon Hadlington
New 'click' reaction to modify proteins Chemists in the US have discovered a new way to attach small molecules to proteins and peptides under mild, aqueous reaction conditions. mark for My Articles similar articles
Chemistry World
November 1, 2007
Richard Van Noorden
Step Change for Organic Synthesis US chemists discovered how to attack a complex molecule's unreactive carbon-hydrogen bonds, without resorting to wasteful synthetic aids like protecting and directing groups. mark for My Articles similar articles
Chemistry World
December 3, 2009
Simon Hadlington
C-H Bond Activation Takes the Relaxing Route Chemists have uncovered a key factor that helps determine the reactivity of a C-H bond to oxidation. mark for My Articles similar articles
Chemistry World
October 13, 2011
Phillip Broadwith
Following Electrons' Chemical Reaction Quickstep The oscillating electronic states of molecules nearby and passing through a conical intersection can now be probed directly. mark for My Articles similar articles
Chemistry World
December 13, 2009
Lewis Brindley
Breaking the strongest bonds Chemists have uncovered a way to sever two of the strongest bonds in chemistry - in dinitrogen and carbon monoxide - and make useful organic compounds. mark for My Articles similar articles
Chemistry World
February 4, 2011
Elinor Richards
Strychnine in just six steps Strychnine, best known as a poison but also used medicinally as a stimulant, can now be synthesised in just six steps, say US scientists. mark for My Articles similar articles
Chemistry World
August 30, 2009
Phillip Broadwith
C-H oxidation proves its worth US researchers are going against the grain of total synthesis and developing new approaches to complex molecules. mark for My Articles similar articles
Chemistry World
February 22, 2008
James Mitchell Crow
Rhodium Fast Tracks Route to Lactones Chemists in Canada have developed an efficient new way to make lactones, chemical components of many natural products and drugs. mark for My Articles similar articles
Chemistry World
January 15, 2010
Andy Extance
Quantum computer hits hydrogen bullseye A basic quantum computer has successfully tackled one of the most challenging tasks facing chemists today - calculating molecular energy from basic scientific principles. mark for My Articles similar articles
Chemistry World
June 23, 2015
Matthew Gunther
Photo-catalysts shine light on chemical bond making A team of scientists from Israel and Germany have manipulated bond formation in a chemical reaction using high power lasers mark for My Articles similar articles
Chemistry World
October 2009
Column: In the pipeline Derek Lowe discusses the problem of leaning too heavily on favorite reactions mark for My Articles similar articles
Chemistry World
June 23, 2015
Philip Ball
Ultra-bright x-rays film molecular reaction A team working at the Stanford Linear Collider in California claims to have made 'the first molecular movie' using ultra-fast x-ray scattering from molecules as they undergo a chemical reaction. mark for My Articles similar articles
Chemistry World
August 22, 2011
Jon Cartwright
Manmade molecular machine goes to work Manmade molecules can generate similar forces to natural molecular machines, and could help chemists to design artificial molecular machines for meaningful tasks. mark for My Articles similar articles
Chemistry World
September 20, 2007
Lewis Brindley
New Catalyst Rings the Changes Organic chemists in the US have developed a method to control the stereochemistry of a useful intramolecular Diels-Alder reaction. mark for My Articles similar articles
Chemistry World
December 8, 2011
Sarah Farley
Capturing Compounds in Cages for Chemical Control Scientists from the UK have used a molecular capsule to control the reactivity of an organic compound. mark for My Articles similar articles
Chemistry World
May 13, 2013
Philip Ball
The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded? mark for My Articles similar articles
Chemistry World
May 13, 2014
Jennifer Newton
Blurred bonds rationalized by heavy atom tunnelling A new theoretical study of anti-aromatic systems has attributed the unusual way that their I -bonds shift to quantum tunnelling. mark for My Articles similar articles
Chemistry World
July 13, 2015
Philip Ball
First snapshot of elusive intermediate supplies surprise A team near Zurich in Switzerland, has been able to take a single-molecule snapshot of an intermediate in a common class of organic reactions. mark for My Articles similar articles
Chemistry World
May 6, 2009
Nina Notman
Polymers feel the force A new way to make force-sensitive polymers that respond to stress by changing colour has been designed by a multidisciplinary team in the US. mark for My Articles similar articles
Chemistry World
January 29, 2012
Andy Extance
Calculations reveal carbon-carbon quadruple bond C 2's two carbon atoms aren't joined by a double bond as usually thought, or even a triple bond, but in fact a quadruple bond. mark for My Articles similar articles
Chemistry World
September 12, 2010
Simon Hadlington
Isotope effect seen on single molecule The isotope effect - where the rate of a reaction is altered depending on the presence of a given isotopic atom in the reactant - is a key tool for elucidating reaction mechanisms mark for My Articles similar articles
Reactive Reports
Issue 63
David Bradley
Chemists Go Round the Bend Chemists often think of molecular wires as "shape-persistent" rods with limited flexibility, but researchers have now shown that molecular wires can be bent into ring shapes. mark for My Articles similar articles
Chemistry World
April 28, 2011
Simon Hadlington
New method for aromatic coupling Chemists in Switzerland have developed a way to couple aromatic rings through the Friedel-Crafts mechanism - something many people would have believed impossible. mark for My Articles similar articles
Chemistry World
August 23, 2006
Simon Hadlington
Laser Light Cast on Quantum Evolution Researchers have demonstrated for the first time why a technique called coherent control is able to break molecular bonds selectively using finely-tuned pulses of laser light. mark for My Articles similar articles
Chemistry World
January 6, 2010
Phillip Broadwith
Enzymes do the twist The way enzyme catalysts bind molecules to speed up their reactions is not as simple as once thought, say chemists from the UK and Spain. mark for My Articles similar articles
Chemistry World
January 22, 2007
Richard Van Noorden
First Synchrotron for Neutral Molecules Scientists have built and demonstrated the first synchrotron to work on neutral molecules. It could be used to study collisions of cold, slow-moving molecules, allowing chemists to probe their behavior with a resolution impossible to achieve at higher temperatures. mark for My Articles similar articles
Chemistry World
April 30, 2008
Lewis Brindley
Chemical compass clue to migration mystery Trying to identify the mysterious innate compass that many animals use to navigate the globe, chemists at the University of Oxford, UK, have shown for the first time that the Earth's magnetic field can influence the outcome of a chemical reaction. mark for My Articles similar articles
Chemistry World
September 24, 2009
Phillip Broadwith
Carbon can't but tin can US chemists have discovered that distannynes - tin-based analogues of acetylenes - can react reversibly with ethene to make cyclic complexes. mark for My Articles similar articles
Chemistry World
January 29, 2015
Santiago Alvarez
What we mean when we talk about bonds The chemical bond is still a matter of lively debate among chemists, even a century after Gilbert Lewis introduced his electron pair bonding concept. mark for My Articles similar articles
Chemistry World
May 29, 2015
Derek Lowe
Magic molecule modifiers The synthesis of a new organic molecule can be approached in several ways. mark for My Articles similar articles
Chemistry World
September 12, 2013
Andy Extance
Sulfur difluoride dimer exposes bonding strangeness Calculations on unusual bonding in the sulfur difluoride dimer FSSF 3 have provided evidence to help explain why some compounds don't follow long-established chemical rules. mark for My Articles similar articles
Chemistry World
May 24, 2007
James Mitchell Crow
Palladium Coupling in Fewer Steps Look out Suzuki - Canadian chemists have successfully joined up simple benzene ring-like aromatics without any pre-activation. mark for My Articles similar articles
Chemistry World
November 3, 2008
Simon Hadlington
Organic synthesis set for auto-pilot Peptides are routinely made by machines that couple together amino acid components. Could organic synthesis ever get this simple? mark for My Articles similar articles
Chemistry World
February 28, 2012
Nina Notman
Observing Charge Distribution in Molecules The distribution of charge across a single molecule has been imaged for the first time by Swiss scientists. It is hoped that this work may eventually lead to electronic devices consisting of organic molecules. mark for My Articles similar articles
Chemistry World
November 17, 2011
James Urquhart
A Thermoset Plastic That Bends Like a Thermoplastic French scientists have created a new lightweight plastic that is as strong and stable as other thermoset materials such as Bakelite, yet can be easily reworked and reshaped when heated. mark for My Articles similar articles
Chemistry World
December 9, 2013
Jessica Cocker
Hydrogen breaks strong bonds with brute force A method developed by Leo Lau of Western University in Canada and colleagues can break C -- H bonds without damaging the rest of the molecule. mark for My Articles similar articles
Chemistry World
March 9, 2007
Michael Gross
Nanowires go Round the Bend Chemists have bent an apparently linear molecular wire into a closed circle, creating a conducting ring just 3 nanometers across. mark for My Articles similar articles
Chemistry World
March 25, 2012
Phillip Broadwith
Germanium-Oxygen Double Bond Takes Centre Stage The first compound with a germanium-oxygen double bond has been created by Japanese scientists. mark for My Articles similar articles