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Chemistry World March 9, 2006 Katharine Sanderson |
Covalent Bonds Crack Under the Strain Chemists must consider engineering principles when designing molecules following news that tough carbon-to-carbon bonds break easily under mechanical strain. |
Chemistry World September 15, 2011 David Bradley |
Sound Approach to Unclicking Click Chemistry Ultrasound can be used to physically release a triazole from a polymer-companies. |
Chemistry World March 31, 2009 Lewis Brindley |
Giving molecules a stretch A simple way to stretch small molecules and measure the forces at play has been developed by researchers in the US. |
Chemistry World March 3, 2014 David Bradley |
Mechanical stress pulls cyclization into shape Researchers at the Ruhr University Bochum, in Germany, have calculated that enediyne toxins, compounds used as anticancer drugs, might undergo Bergman cyclization when put under stress. |
Chemistry World October 12, 2006 Richard Van Noorden |
Lasers on the Energy Ski Slope Researchers have shown that intense laser-light pulses can act as catalysts, controlling the end products of a chemical reaction without themselves being absorbed. |
Chemistry World January 27, 2010 Phillip Broadwith |
Cracking carbon-carbon bonds Chemists in the US have discovered a tungsten complex that can break a strong carbon-carbon bond in an aromatic ring. |
Chemistry World July 16, 2009 Simon Hadlington |
Strange vibrations Researchers in Taiwan have shown that in a relatively simple molecular system the induced vibrations can inhibit the breaking of the bond and slow the reaction down. |
Chemistry World June 13, 2012 Simon Hadlington |
Exploding molecule provides 3D bond images Researchers from the US and Germany have demonstrated a new way to obtain accurate three-dimensional images of molecules, with precise measurements of the geometry of the molecule's chemical bonds. |
Chemistry World September 9, 2009 Lewis Brindley |
Daisy-chain polymers bring artificial muscles a step closer American chemists have made molecular 'daisy-chains' containing threaded rings that can be pulled taut or slackened by chemical stimuli. |
Chemistry World April 6, 2009 Nina Notman |
Torn catalysts help polymers heal themselves Catalysts that are activated by a mechanical force tearing them in two have been designed by Dutch scientists. |
Chemistry World March 8, 2009 Nina Notman |
Polymer Crossroads Act as Tiny Reactors Scientists in the US have taken inspiration from a Dutch painter to create ultrasmall chemical reactors at the junctions of overlapping polymer nanofibres |
Chemistry World November 13, 2008 Hayley Birch |
Reactions Studied by Stop Motion Japanese and Israeli scientists have developed a technique that can track whole-molecule changes that occur during extremely rapid reactions. |
Chemistry World January 19, 2010 Simon Hadlington |
New 'click' reaction to modify proteins Chemists in the US have discovered a new way to attach small molecules to proteins and peptides under mild, aqueous reaction conditions. |
Chemistry World November 1, 2007 Richard Van Noorden |
Step Change for Organic Synthesis US chemists discovered how to attack a complex molecule's unreactive carbon-hydrogen bonds, without resorting to wasteful synthetic aids like protecting and directing groups. |
Chemistry World December 3, 2009 Simon Hadlington |
C-H Bond Activation Takes the Relaxing Route Chemists have uncovered a key factor that helps determine the reactivity of a C-H bond to oxidation. |
Chemistry World October 13, 2011 Phillip Broadwith |
Following Electrons' Chemical Reaction Quickstep The oscillating electronic states of molecules nearby and passing through a conical intersection can now be probed directly. |
Chemistry World December 13, 2009 Lewis Brindley |
Breaking the strongest bonds Chemists have uncovered a way to sever two of the strongest bonds in chemistry - in dinitrogen and carbon monoxide - and make useful organic compounds. |
Chemistry World February 4, 2011 Elinor Richards |
Strychnine in just six steps Strychnine, best known as a poison but also used medicinally as a stimulant, can now be synthesised in just six steps, say US scientists. |
Chemistry World August 30, 2009 Phillip Broadwith |
C-H oxidation proves its worth US researchers are going against the grain of total synthesis and developing new approaches to complex molecules. |
Chemistry World February 22, 2008 James Mitchell Crow |
Rhodium Fast Tracks Route to Lactones Chemists in Canada have developed an efficient new way to make lactones, chemical components of many natural products and drugs. |
Chemistry World January 15, 2010 Andy Extance |
Quantum computer hits hydrogen bullseye A basic quantum computer has successfully tackled one of the most challenging tasks facing chemists today - calculating molecular energy from basic scientific principles. |
Chemistry World June 23, 2015 Matthew Gunther |
Photo-catalysts shine light on chemical bond making A team of scientists from Israel and Germany have manipulated bond formation in a chemical reaction using high power lasers |
Chemistry World October 2009 |
Column: In the pipeline Derek Lowe discusses the problem of leaning too heavily on favorite reactions |
Chemistry World June 23, 2015 Philip Ball |
Ultra-bright x-rays film molecular reaction A team working at the Stanford Linear Collider in California claims to have made 'the first molecular movie' using ultra-fast x-ray scattering from molecules as they undergo a chemical reaction. |
Chemistry World August 22, 2011 Jon Cartwright |
Manmade molecular machine goes to work Manmade molecules can generate similar forces to natural molecular machines, and could help chemists to design artificial molecular machines for meaningful tasks. |
Chemistry World September 20, 2007 Lewis Brindley |
New Catalyst Rings the Changes Organic chemists in the US have developed a method to control the stereochemistry of a useful intramolecular Diels-Alder reaction. |
Chemistry World December 8, 2011 Sarah Farley |
Capturing Compounds in Cages for Chemical Control Scientists from the UK have used a molecular capsule to control the reactivity of an organic compound. |
Chemistry World May 13, 2013 Philip Ball |
The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded? |
Chemistry World May 13, 2014 Jennifer Newton |
Blurred bonds rationalized by heavy atom tunnelling A new theoretical study of anti-aromatic systems has attributed the unusual way that their I -bonds shift to quantum tunnelling. |
Chemistry World July 13, 2015 Philip Ball |
First snapshot of elusive intermediate supplies surprise A team near Zurich in Switzerland, has been able to take a single-molecule snapshot of an intermediate in a common class of organic reactions. |
Chemistry World May 6, 2009 Nina Notman |
Polymers feel the force A new way to make force-sensitive polymers that respond to stress by changing colour has been designed by a multidisciplinary team in the US. |
Chemistry World January 29, 2012 Andy Extance |
Calculations reveal carbon-carbon quadruple bond C 2's two carbon atoms aren't joined by a double bond as usually thought, or even a triple bond, but in fact a quadruple bond. |
Chemistry World September 12, 2010 Simon Hadlington |
Isotope effect seen on single molecule The isotope effect - where the rate of a reaction is altered depending on the presence of a given isotopic atom in the reactant - is a key tool for elucidating reaction mechanisms |
Reactive Reports Issue 63 David Bradley |
Chemists Go Round the Bend Chemists often think of molecular wires as "shape-persistent" rods with limited flexibility, but researchers have now shown that molecular wires can be bent into ring shapes. |
Chemistry World April 28, 2011 Simon Hadlington |
New method for aromatic coupling Chemists in Switzerland have developed a way to couple aromatic rings through the Friedel-Crafts mechanism - something many people would have believed impossible. |
Chemistry World August 23, 2006 Simon Hadlington |
Laser Light Cast on Quantum Evolution Researchers have demonstrated for the first time why a technique called coherent control is able to break molecular bonds selectively using finely-tuned pulses of laser light. |
Chemistry World January 6, 2010 Phillip Broadwith |
Enzymes do the twist The way enzyme catalysts bind molecules to speed up their reactions is not as simple as once thought, say chemists from the UK and Spain. |
Chemistry World January 22, 2007 Richard Van Noorden |
First Synchrotron for Neutral Molecules Scientists have built and demonstrated the first synchrotron to work on neutral molecules. It could be used to study collisions of cold, slow-moving molecules, allowing chemists to probe their behavior with a resolution impossible to achieve at higher temperatures. |
Chemistry World April 30, 2008 Lewis Brindley |
Chemical compass clue to migration mystery Trying to identify the mysterious innate compass that many animals use to navigate the globe, chemists at the University of Oxford, UK, have shown for the first time that the Earth's magnetic field can influence the outcome of a chemical reaction. |
Chemistry World September 24, 2009 Phillip Broadwith |
Carbon can't but tin can US chemists have discovered that distannynes - tin-based analogues of acetylenes - can react reversibly with ethene to make cyclic complexes. |
Chemistry World January 29, 2015 Santiago Alvarez |
What we mean when we talk about bonds The chemical bond is still a matter of lively debate among chemists, even a century after Gilbert Lewis introduced his electron pair bonding concept. |
Chemistry World May 29, 2015 Derek Lowe |
Magic molecule modifiers The synthesis of a new organic molecule can be approached in several ways. |
Chemistry World September 12, 2013 Andy Extance |
Sulfur difluoride dimer exposes bonding strangeness Calculations on unusual bonding in the sulfur difluoride dimer FSSF 3 have provided evidence to help explain why some compounds don't follow long-established chemical rules. |
Chemistry World May 24, 2007 James Mitchell Crow |
Palladium Coupling in Fewer Steps Look out Suzuki - Canadian chemists have successfully joined up simple benzene ring-like aromatics without any pre-activation. |
Chemistry World November 3, 2008 Simon Hadlington |
Organic synthesis set for auto-pilot Peptides are routinely made by machines that couple together amino acid components. Could organic synthesis ever get this simple? |
Chemistry World February 28, 2012 Nina Notman |
Observing Charge Distribution in Molecules The distribution of charge across a single molecule has been imaged for the first time by Swiss scientists. It is hoped that this work may eventually lead to electronic devices consisting of organic molecules. |
Chemistry World November 17, 2011 James Urquhart |
A Thermoset Plastic That Bends Like a Thermoplastic French scientists have created a new lightweight plastic that is as strong and stable as other thermoset materials such as Bakelite, yet can be easily reworked and reshaped when heated. |
Chemistry World December 9, 2013 Jessica Cocker |
Hydrogen breaks strong bonds with brute force A method developed by Leo Lau of Western University in Canada and colleagues can break C -- H bonds without damaging the rest of the molecule. |
Chemistry World March 9, 2007 Michael Gross |
Nanowires go Round the Bend Chemists have bent an apparently linear molecular wire into a closed circle, creating a conducting ring just 3 nanometers across. |
Chemistry World March 25, 2012 Phillip Broadwith |
Germanium-Oxygen Double Bond Takes Centre Stage The first compound with a germanium-oxygen double bond has been created by Japanese scientists. |