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Chemistry World
March 1, 2012
David Bradley
Roaming reactions double up in atmospheric chemistry Chemists have found a chemical reaction that ignores its reaction coordinate and seemingly bypasses the conventional mechanics of transition state theory to display two distinct 'roaming' mechanisms. mark for My Articles similar articles
Chemistry World
January 25, 2007
Richard Van Noorden
Water Surprise for Atmospheric Scientists Lone water molecules can catalyze reactions between atmospheric gases, scientists have confirmed, throwing a wrench in the works of supposedly simple atmospheric chemistry. mark for My Articles similar articles
Chemistry World
February 24, 2012
Yuandi Li
Computers look at life-giving reactions in space Theoretical chemistry could answer some questions about how life on earth originated, say Australian researchers. mark for My Articles similar articles
Chemistry World
January 6, 2010
Phillip Broadwith
Enzymes do the twist The way enzyme catalysts bind molecules to speed up their reactions is not as simple as once thought, say chemists from the UK and Spain. mark for My Articles similar articles
Chemistry World
July 16, 2009
Simon Hadlington
Strange vibrations Researchers in Taiwan have shown that in a relatively simple molecular system the induced vibrations can inhibit the breaking of the bond and slow the reaction down. mark for My Articles similar articles
Chemistry World
June 10, 2011
Laura Howes
Quantum tunnelling creates the 'wrong' molecule Protons takes a quantum leap in carbene reaction to give chemists a surprise mark for My Articles similar articles
Chemistry World
September 30, 2009
Simon Haddlington
Porous networks trap reactive intermediates Chemists in Japan have shown how it is possible to take sequential x-ray snapshots of chemical reactions taking place within molecular-sized 'reaction chambers', capturing the crystal structures of short-lived reactive intermediates. mark for My Articles similar articles
Chemistry World
November 6, 2008
James Mitchell Crow
Double reactor makes hydrogen and syngas Two chemical reactions key to producing future fuels can be linked together in a single membrane-based reactor to increase their efficiency, say Chinese chemists. mark for My Articles similar articles
Chemistry World
June 23, 2015
Philip Ball
Ultra-bright x-rays film molecular reaction A team working at the Stanford Linear Collider in California claims to have made 'the first molecular movie' using ultra-fast x-ray scattering from molecules as they undergo a chemical reaction. mark for My Articles similar articles
Chemistry World
February 13, 2015
Andy Extance
X-ray laser snaps first bond-forming transition state Using data from x-ray lasers scientists have reconstructed the formation of the carbon monoxide oxidation transition state. mark for My Articles similar articles
Chemistry World
January 12, 2014
Andy Extance
Rocket reactor forces space hydrogen rethink Scientists have pushed low-temperature experimentation and computational chemistry to their limits to better understand hydrogen fluoride, which astronomers use to study regions of space that are otherwise hard to image. mark for My Articles similar articles
Chemistry World
February 20, 2008
Simon Hadlington
Chemists Tame Acetaldehyde German chemists have prevented acetaldehyde from running amok during the Mannich reaction, opening up new avenues in drug discovery. mark for My Articles similar articles
Chemistry World
November 3, 2010
Andy Extance
Hydrogen bond set to be redefined The world authority on chemical nomenclature is preparing to scrap the familiar hydrogen bond definition, in light of recent evidence about its true nature. mark for My Articles similar articles
Chemistry World
June 23, 2015
Matthew Gunther
Photo-catalysts shine light on chemical bond making A team of scientists from Israel and Germany have manipulated bond formation in a chemical reaction using high power lasers mark for My Articles similar articles
Chemistry World
July 5, 2007
Michael Gross
Cold Chemistry Chemical reactions at extremely low temperatures can run at surprisingly fast rates and astrochemists have begun to figure out why. mark for My Articles similar articles
Chemistry World
April 4, 2008
James Mitchell Crow
More to Catalysis Than Meets the Eye Catalysts are more than just a reactive surface. Changes beneath a metal's skin can completely change the course of a reaction. mark for My Articles similar articles
Chemistry World
September 9, 2011
James Mitchell Crow
High-throughput catalyst screening for the masses Using nothing more than the standard chemistry lab equipment, researchers in the US have successfully turned the discovery of new catalytic reactions into a high-throughput process. mark for My Articles similar articles
Chemistry World
March 21, 2007
Richard Van Noorden
Forcing a Reaction US chemists have forced molecules to react by ripping their bonds apart with ultrasound. The scientists carefully stretched one targeted bond until it snapped, guiding the molecule's subsequent reaction into pathways forbidden by conventional chemistry. mark for My Articles similar articles
Chemistry World
December 15, 2015
Philippa Matthews
Getting the measure of transition states For the first time researchers have access to previously unmeasurable rotation constants and frequencies of the transition state. mark for My Articles similar articles
Chemistry World
July 31, 2014
Caryl Richards
New source of hydroxyl radicals found in the clouds An international collaboration of scientists has discovered a previously unidentified source of tropospheric hydroxyl radicals generated by the interaction of ozone with the surface of clouds. mark for My Articles similar articles
Chemistry World
December 16, 2011
Kate McAlpine
Radical experiment assesses interstellar nitrogen Radical reactions are challenging to measure at cold temperatures, but an international team of researchers have recently clocked the rate for atomic nitrogen and hydroxyl radicals at 56K. mark for My Articles similar articles
Chemistry World
March 17, 2015
Andy Extance
Reaction map suggests meteorite chemistry route to life UK chemists have found a reaction network that they believe shows that 'pretty much everyone' working on life's molecular origins is wrong -- but also 'right, in a sense'. mark for My Articles similar articles
Chemistry World
July 23, 2015
Richard Massey
Photoredox catalysis mechanisms seen in new light A debate over whether photoredox-catalyzed reactions proceed via chain processes may now be settled, thanks to new mechanistic insight brought to light by scientists in the US. mark for My Articles similar articles
Chemistry World
July 14, 2009
Phillip Broadwith
Multicomponent reactions step up a gear Dutch chemists have taken multicomponent reactions to the next level, combining a total of eight different starting materials in a single flask, bringing together three different multicomponent reactions and making nine new bonds in a single step. mark for My Articles similar articles
Chemistry World
September 4, 2012
Derek Lowe
Light in the Lab We organic chemists do terrible things to our molecules. How about dissolving the starting materials up in a flask, shining a light into the mixture and coming back later to find it transformed into your product? That's photochemistry. mark for My Articles similar articles
Chemistry World
May 8, 2012
Phillip Broadwith
Keep stirring that Suzuki The shape of your reaction vessel can influence the behavior of organotrifluoroborate compounds in Suzuki cross-coupling reactions, say chemists in the UK. mark for My Articles similar articles
Chemistry World
June 18, 2013
Rowan Frame
Hydrogen generation using sunlight Scientists from Spain have found a catalyst that can use sunlight to power an important industrial reaction for the production of hydrogen at ambient temperatures. mark for My Articles similar articles
Chemistry World
May 29, 2015
Derek Lowe
Magic molecule modifiers The synthesis of a new organic molecule can be approached in several ways. mark for My Articles similar articles
Chemistry World
October 2009
Column: In the pipeline Derek Lowe discusses the problem of leaning too heavily on favorite reactions mark for My Articles similar articles
Chemistry World
April 25, 2014
Derek Lowe
Engineering serendipity At this stage in the world of organic chemistry, you'd have to think that many of the great reactions that can be stumbled across with known reagents have probably been found. mark for My Articles similar articles
Chemistry World
December 5, 2012
Phillip Broadwith
Chemical reactions in hot water Chinese and Japanese chemists have highlighted hot water's ability to promote unexpected reactions without any other reagents or catalysts. The work should expand our understanding of how to harness the physicochemical properties of water to potentially replace more complex reagents and catalysts. mark for My Articles similar articles
Chemistry World
October 2007
Bernard Bulkin
Can Chemistry Save the Planet? If we are to scale back our greenhouse gas emissions without society juddering to a halt, 21st century transport will need 21st century fuels. And of all the sciences, it is chemistry that is best placed to deliver them. mark for My Articles similar articles
Chemistry World
August 22, 2014
Derek Lowe
Death of a reagent Anyone who's been practicing organic chemistry for a while can think back to reactions and reagents that were once in far wider use than they are today. mark for My Articles similar articles
Chemistry World
November 2007
Derek Lowe
Column: In the Pipeline Chemists are finally going with the flow. mark for My Articles similar articles
Chemistry World
January 25, 2013
Derek Lowe
Name reactions: how does the label stick? Some of these names go back to the 19th century, and many more of them come from the first decades of the 20th. Once in a while, I wonder if the tradition is dying out. Are we still naming chemical reactions after their discoverers? mark for My Articles similar articles
Chemistry World
November 25, 2014
James Urquhart
Nanomolar chemistry enables 1500 experiments in a single day Chemists have conducted over 1500 chemistry experiments in under a day thanks to a miniaturized, high throughput automation platform they developed for identifying how synthetic molecules react under various conditions. mark for My Articles similar articles
Chemistry World
September 26, 2012
Derek Lowe
Under pressure Someone interviewing for a synthetic chemistry position had better know his or her organic chemistry. It's fair to ask questions that will make sure of that. But does a candidate need to know the curly-arrow details of reactions that they'll never run? mark for My Articles similar articles
Chemistry World
November 16, 2007
Richard Van Noorden
Tantalizing Boost for Hydrogen Storage US chemists have announced the discovery of a new hydrogen-storage material, which they say stores large amounts of the gas at room temperature. mark for My Articles similar articles
Chemistry World
August 2008
Column: In the pipeline Problems develop when there are too few workhorse reactions, which may well generate compounds that are too similar to each other. Are we at that stage now? mark for My Articles similar articles
Reactive Reports
December 2006
David Bradley
Dick Wife An interview with the chemical IT scientist and co-founder of SORD, a scientific publishing company that seeks to solve the problem of organizing the myriad of undocumented chemistry and the chaotic mess of the commercial database. mark for My Articles similar articles
Chemistry World
May 26, 2015
Catching the runaways I think each cohort of industrial chemists has a runaway industrial reaction that defines their generation. mark for My Articles similar articles
Chemistry World
August 2007
Derek Lowe
Opinion: In the Pipeline Process chemists just don't get the credit they deserve. mark for My Articles similar articles