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Chemistry World
June 24, 2010
Phillip Broadwith
Aryl rings get a fluorine fix A mild and effective method for coupling trifluoromethyl groups on to aryl rings has been developed by US chemists. mark for My Articles similar articles
Chemistry World
June 12, 2015
David Bradley
Copper click chemistry mechanism unravelled Both the mono- and bis-copper pathways are active in the CuAAC reaction, but the latter is kinetically favored. mark for My Articles similar articles
Chemistry World
March 19, 2009
Manisha Lalloo
Copper catalysts give meta aromatics UK Researchers have discovered that, simply by using a copper catalyst, they are able to perform tricky substitution reactions at a difficult position on benzene rings mark for My Articles similar articles
Chemistry World
June 8, 2014
David Bradley
Carbon--carbon couplings go 3D Chemists have devised a new stereospecific coupling reaction for electron-rich aromatics using secondary and tertiary boronic esters that works under mild conditions. mark for My Articles similar articles
Chemistry World
August 14, 2014
Elisabeth Ratcliffe
Photoredox route to medically-important heterocycles Researchers in the US have developed a new photo catalyzed coupling reaction that could provide a pathway to a huge number of biologically active compounds. mark for My Articles similar articles
Chemistry World
July 3, 2015
Andy Extance
Copper catalysis overcomes double bond trouble Some carbon-carbon double bonds seem too unreactive for synthetic use -- but that's just how chemists in the US are now exploiting them. mark for My Articles similar articles
Chemistry World
January 13, 2011
Sarah Corcoran
Unclogging the problems of flow chemistry US scientists have found a way to stop solid byproducts clogging channels in continuous flow reactors, a problem that has hampered their progress for use in manufacturing pharmaceuticals. mark for My Articles similar articles
Chemistry World
December 16, 2011
Kate McAlpine
Radical experiment assesses interstellar nitrogen Radical reactions are challenging to measure at cold temperatures, but an international team of researchers have recently clocked the rate for atomic nitrogen and hydroxyl radicals at 56K. mark for My Articles similar articles
Chemistry World
March 31, 2011
Mike Brown
Electrifying polymers Scientists in the US and Italy have used electricity to control atom transfer radical polymerisation reactions, industrially significant reactions for producing plastics. mark for My Articles similar articles
Chemistry World
November 2010
Carbon Couplers Take the Prize Three giants of organic chemistry, who pioneered palladium-catalysed cross coupling reactions, have shared this year's Nobel prize. mark for My Articles similar articles
Chemistry World
October 12, 2015
Emma Stoye
Chemistry Nobel laureate Richard Heck dies Richard Heck, the organic chemist who shared the 2010 chemistry Nobel prize with for developing palladium-catalyzed cross coupling reactions, has died aged 84. mark for My Articles similar articles
Chemistry World
September 4, 2013
Mark Peplow
Iron catalyst offers nitrogenase clues It is one of the most enduring mysteries in chemistry: how do certain bacteria fix nitrogen from the air? mark for My Articles similar articles
Chemistry World
November 25, 2014
James Urquhart
Nanomolar chemistry enables 1500 experiments in a single day Chemists have conducted over 1500 chemistry experiments in under a day thanks to a miniaturized, high throughput automation platform they developed for identifying how synthetic molecules react under various conditions. mark for My Articles similar articles
Chemistry World
December 20, 2007
Richard Van Noorden
Off-the-Peg Organic Synthesis Goes Commercial Chemists have created an efficient way to make small molecules by repeatedly using just one coupling reaction to clip together pre-prepared chemical fragments is going commercial. mark for My Articles similar articles
Chemistry World
April 28, 2011
Simon Hadlington
New method for aromatic coupling Chemists in Switzerland have developed a way to couple aromatic rings through the Friedel-Crafts mechanism - something many people would have believed impossible. mark for My Articles similar articles
Chemistry World
November 2, 2011
Phillip Broadwith
Do Carbyne Radicals Really Exist in Aqueous Solution? Carbyne radicals are ejected from molybdenum clusters in water and react together to make lots of organic molecules, including alkynes mark for My Articles similar articles
Chemistry World
October 2009
Column: In the pipeline Derek Lowe discusses the problem of leaning too heavily on favorite reactions mark for My Articles similar articles
Chemistry World
February 2, 2011
Elinor Richards
Gold going it alone Spanish scientists have proved that gold alone can catalyse cross-coupling reactions following a claim made last year that palladium impurities in the gold are essential for the catalysis. mark for My Articles similar articles
Chemistry World
August 2008
Column: In the pipeline Problems develop when there are too few workhorse reactions, which may well generate compounds that are too similar to each other. Are we at that stage now? mark for My Articles similar articles
Chemistry World
September 24, 2008
Lewis Brindley
Copper Future for Solar Cells Rare ruthenium complexes that are a key component of dye-sensitized solar cells could be replaced by molecules based on copper. mark for My Articles similar articles
Chemistry World
August 22, 2014
Derek Lowe
Death of a reagent Anyone who's been practicing organic chemistry for a while can think back to reactions and reagents that were once in far wider use than they are today. mark for My Articles similar articles
Chemistry World
November 2007
Derek Lowe
Column: In the Pipeline Chemists are finally going with the flow. mark for My Articles similar articles
Chemistry World
January 25, 2013
Derek Lowe
Name reactions: how does the label stick? Some of these names go back to the 19th century, and many more of them come from the first decades of the 20th. Once in a while, I wonder if the tradition is dying out. Are we still naming chemical reactions after their discoverers? mark for My Articles similar articles
Chemistry World
January 15, 2010
Kate McAlpine
Capturing carbon with copper A team of researchers in the Netherlands have devised a trap that can pull carbon dioxide out of the air. mark for My Articles similar articles
Chemistry World
January 2012
Paul Docherty
Column: Totally Synthetic What a Japanese team demonstrates in this synthesis of dragmacidin D is the state of the art, uniting all the key fragments using C-H bond couplings. mark for My Articles similar articles
Chemistry World
November 3, 2008
Simon Hadlington
Organic synthesis set for auto-pilot Peptides are routinely made by machines that couple together amino acid components. Could organic synthesis ever get this simple? mark for My Articles similar articles
Chemistry World
July 25, 2014
Polly Wilson
Uranium complexes unlock feedstock potential of carbon dioxide European scientists have synthesized uranium complexes that take them a step closer to producing commodity chemicals from carbon dioxide. mark for My Articles similar articles
Chemistry World
July 1, 2012
Paul Docherty
Vincorine Cage-structured natural products are some of the most appealing (if perhaps not appetising) targets for organic chemists -- perhaps due to their obvious intricacy of form, but also because of their structural rigidity. mark for My Articles similar articles
Chemistry World
September 26, 2012
Derek Lowe
Under pressure Someone interviewing for a synthetic chemistry position had better know his or her organic chemistry. It's fair to ask questions that will make sure of that. But does a candidate need to know the curly-arrow details of reactions that they'll never run? mark for My Articles similar articles
Chemistry World
September 30, 2011
Colourful Research Jeremy Smith talks about why choosing inorganic chemistry was a case of columns versus color. mark for My Articles similar articles
Reactive Reports
Issue 31
David Bradley
Tired of old tires A more environmentally friendly car tire made from silica and rubber has low rolling resistance and uses five percent less fuel than standard tires. The hard part is getting silica and rubber to mix. mark for My Articles similar articles