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Chemistry World
October 29, 2009
Phillip Broadwith
Two metals are better than one UK chemists have developed reagents that can metallate ethers and ethene at room temperature without them disintegrating. mark for My Articles similar articles
Chemistry World
April 12, 2012
Simon Hadlington
Recruiting electrophiles for organic cross-coupling Chemists in the US have taken an unconventional approach to carbon cross-coupling and in doing so have potentially opened the door to the rapid and efficient synthesis of a wide range of organic compounds. mark for My Articles similar articles
Chemistry World
May 29, 2015
Derek Lowe
Magic molecule modifiers The synthesis of a new organic molecule can be approached in several ways. mark for My Articles similar articles
Chemistry World
October 5, 2006
Mark Peplow
Boron Shows Its Negative Side A molecule that hosts a negatively-charged boron atom could prove to be an exciting addition to the chemist's toolbox, according to researchers who have isolated the anion as its lithium salt. mark for My Articles similar articles
Chemistry World
March 19, 2009
Manisha Lalloo
Copper catalysts give meta aromatics UK Researchers have discovered that, simply by using a copper catalyst, they are able to perform tricky substitution reactions at a difficult position on benzene rings mark for My Articles similar articles
Chemistry World
November 8, 2007
James Mitchell Crow
First Mg(I) Complex Made Chemists have created the first stable magnesium(I) compounds, a breakthrough for a metal whose chemistry is ruled by the oxidation state. mark for My Articles similar articles
Chemistry World
March 2, 2015
Andy Extance
Chemists zinc up 'aromatic' metal cubes Researchers in China and the US have synthesized polyzinc clusters that have pushed back the boundaries of the kind of aromatic structures chemists can make. mark for My Articles similar articles
Chemistry World
October 22, 2009
Simon Hadlington
Carbenes catalyse metal-metal bonds in organometallics Chemists in the US have discovered a novel way to transform organometallic compounds so that new metal-metal bonds are created. mark for My Articles similar articles
Chemistry World
March 22, 2012
Ross McLaren
Back to the future: old reactions to help the new Researchers from the US have delved into the history of organic chemistry to help chemists better predict the effect that functional groups will have on one another within a molecule. mark for My Articles similar articles
Chemistry World
February 21, 2007
Tom Westgate
Complex Organic Molecules Teamed with Iodine Chemists have developed a method for constructing complex halogen-containing organic molecules from simple compounds in a single step. The discovery could pave the way for the synthesis of many potentially useful naturally occurring molecules. mark for My Articles similar articles
Chemistry World
April 26, 2007
Richard Van Noorden
Hydrogen Busters go Synthetic Chemists have created a small molecule which mimics the way natural enzymes chew up hydrogen. The model should inspire designs for new catalysts that can break up hydrogen in fuel cells; or (running in reverse) help produce the fuel for a hydrogen economy. mark for My Articles similar articles
Chemistry World
January 2, 2013
Derek Lowe
Fear of the unknown My mental file drawer labelled 'Terrible Reagents I Have Known' is even larger than the one called 'Lunatics I Have Worked With and their Life-Threatening Ideas'. We organic chemists really do work with some terrible chemicals, and it's up to us to keep them from causing havoc. mark for My Articles similar articles
Reactive Reports
Issue 62
Alumination at last! More powerful solid rocket fuel could be the product of research into a new class of compounds containing aluminum and hydrogen compounds, according to an international research team. mark for My Articles similar articles
Chemistry World
November 27, 2009
Simon Hadlington
A simple way to join an olefin to an arene Chemists in the US have developed a simple and effective way to carry out a key class of reaction in organic synthesis - the bolting an olefin to an aromatic ring. mark for My Articles similar articles
Chemistry World
April 28, 2014
Simon Hadlington
Elusive sigma aromaticity captured Chemists in the US have created a unique transition metal hydride in which the hydrogens form a five-membered aromatic ring, something that had been theorized, but until now never seen. mark for My Articles similar articles
Chemistry World
June 1, 2012
Mike Sutton
A reluctant chemist A century after Francois Auguste Victor Grignard's Nobel prize, organic chemists are still using the reagents he developed. mark for My Articles similar articles
Chemistry World
August 2008
Column: In the pipeline Problems develop when there are too few workhorse reactions, which may well generate compounds that are too similar to each other. Are we at that stage now? mark for My Articles similar articles
Chemistry World
March 25, 2011
Simon Hadlington
New synthesis for chiral anticancer compound The promising anticancer compound nutlin-3 is likely to become more widely available to researchers thanks to a new synthetic protocol developed by US chemists. mark for My Articles similar articles
Chemistry World
September 30, 2009
Simon Haddlington
Porous networks trap reactive intermediates Chemists in Japan have shown how it is possible to take sequential x-ray snapshots of chemical reactions taking place within molecular-sized 'reaction chambers', capturing the crystal structures of short-lived reactive intermediates. mark for My Articles similar articles
Chemistry World
November 2010
Carbon Couplers Take the Prize Three giants of organic chemistry, who pioneered palladium-catalysed cross coupling reactions, have shared this year's Nobel prize. mark for My Articles similar articles
Chemistry World
November 25, 2014
James Urquhart
Nanomolar chemistry enables 1500 experiments in a single day Chemists have conducted over 1500 chemistry experiments in under a day thanks to a miniaturized, high throughput automation platform they developed for identifying how synthetic molecules react under various conditions. mark for My Articles similar articles
Chemistry World
August 2008
Paul Docherty
Column: Totally Synthetic Impersonating nature isn't easy, and biomimetic syntheses are remarkable in two senses. mark for My Articles similar articles
Chemistry World
March 20, 2007
Tom Westgate
Is Your Lab Ready to go Veggie? In a recently published review article, Geoffrey Cordell demonstrates that the greengrocer's could be an unexpected goldmine of sustainable, cheap reagents that would benefit chemistry in developing countries. mark for My Articles similar articles
Chemistry World
July 21, 2010
Lewis Brindley
Selenium-based quinones show anticancer promise The new compounds have great potential for future cancer therapy, and early studies show similar activity to the well-known chemotherapy drug cisplatin, although a selenium-based therapy would cost a fraction of the price. mark for My Articles similar articles
Chemistry World
April 25, 2014
Derek Lowe
Engineering serendipity At this stage in the world of organic chemistry, you'd have to think that many of the great reactions that can be stumbled across with known reagents have probably been found. mark for My Articles similar articles
Chemistry World
July 8, 2010
Phillip Broadwith
Flattening carbon UK researchers have managed to synthesise a molecule with an almost planar four-coordinate carbon atom bonded to two lithium atoms and bulky organic ligands. mark for My Articles similar articles
Reactive Reports
December 2006
David Bradley
Dick Wife An interview with the chemical IT scientist and co-founder of SORD, a scientific publishing company that seeks to solve the problem of organizing the myriad of undocumented chemistry and the chaotic mess of the commercial database. mark for My Articles similar articles
Chemistry World
August 22, 2014
Derek Lowe
Death of a reagent Anyone who's been practicing organic chemistry for a while can think back to reactions and reagents that were once in far wider use than they are today. mark for My Articles similar articles
Chemistry World
November 7, 2013
Polly Wilson
Hydrogen adopts alkali metal position For the first time, scientists have shown that hydrogen can stand in for alkali metals in typical alkali metal structures. mark for My Articles similar articles
Chemistry World
February 27, 2009
Hayley Birch
More data from mixtures via NMR Finnish scientists have developed a new technique for separating out the NMR spectra of compounds in a mixture. mark for My Articles similar articles
Chemistry World
April 13, 2006
Jon Evans
Chemists Bring Alien Molecule Down to Earth Chemists have recreated an alien molecule in the laboratory by synthesising a stable version of the carbene cyclopropenylidene. Cyclopropenylidene was first detected by radio astronomers in 1985, and is now the most abundant cyclic hydrocarbon observed in interstellar space. mark for My Articles similar articles
Chemistry World
November 11, 2015
Aurora Walshe
H 2-free route to actinide hydrides Scientists in the US have shown that phenylsilane is a safer and more convenient replacement for hydrogen gas when synthesizing uranium and thorium hydrides. mark for My Articles similar articles
Chemistry World
February 14, 2008
Simon Hadlington
Molecular Sponges Mop up Carbon Dioxide US researchers have created a range of new chemical 'sponges' that could be used to soak up carbon dioxide from power stations. mark for My Articles similar articles
Chemistry World
June 2008
Column: In the pipeline The author, a medicinal chemist working on preclinical drug discovery, takes a look at the differences between chemists and biologists working on the same team. mark for My Articles similar articles
Chemistry World
August 21, 2008
Fred Campbell
Double bonding with silicon In a landmark for silicon chemistry, US researchers have reported the first stable silicon (0) compound to contain a silicon-silicon double bond. mark for My Articles similar articles
Chemistry World
August 15, 2013
Caryl Richards
First agostic isomers uncovered from two-tone crystals The discovery that two different colored crystals can form from the same molybdenum cation has signalled the first experimental evidence for agostic isomers -- or agostomers -- in organometallic complexes. mark for My Articles similar articles
Chemistry World
February 27, 2013
Simon Hadlington
Supercharging methanol for fuel cells Scientists in Germany and Italy have discovered a way to derive hydrogen gas from methanol at low temperatures and pressures using soluble ruthenium-based 'pincer' catalysts. mark for My Articles similar articles
Chemistry World
August 2007
Derek Lowe
Opinion: In the Pipeline Process chemists just don't get the credit they deserve. mark for My Articles similar articles
Chemistry World
June 1, 2012
Derek Lowe
Peace, love and understanding You'd think that the chemists and biologists working in drug discovery would understand each other pretty well by now. You would be wrong about that. mark for My Articles similar articles
Chemistry World
June 2008
Sarah Houlton
Breaking the rules The author finds out about some chemical tricks that can give a new drug the best possible odds of success mark for My Articles similar articles
Chemistry World
November 14, 2011
Jon Cartwright
Chemists claim metallic hydrogen creation first For over a century, scientists have said it should be possible to turn hydrogen into a metal. Now, a pair of chemists in Germany claim to have finally performed the feat, although others remain skeptical. mark for My Articles similar articles
Chemistry World
July 27, 2009
Simon Hadlington
Peer review by live blogging Blogging can immediately bring together expert opinion on a given topic. Poorly reviewed papers claiming novelty can be expected to be rapidly dissected in the blogosphere, as some chemists have found out. mark for My Articles similar articles
Chemistry World
April 12, 2013
Melissae Fellet
Elusive atmospheric intermediates reveal some secrets Scientists have found further evidence for the existence of an elusive intermediate implicated in chemical reactions that degrade atmospheric pollutants. mark for My Articles similar articles
Chemistry World
January 3, 2012
Simon Hadlington
One-pot synthesis creates anticancer candidates Researchers in Germany have developed a simple, rapid and high-yielding cascade synthesis of a collection of polycyclic compounds that resemble indole alkaloid natural products and which interfere with cell division. mark for My Articles similar articles
Chemistry World
January 25, 2013
Derek Lowe
Name reactions: how does the label stick? Some of these names go back to the 19th century, and many more of them come from the first decades of the 20th. Once in a while, I wonder if the tradition is dying out. Are we still naming chemical reactions after their discoverers? mark for My Articles similar articles
Chemistry World
February 13, 2011
Simon Hadlington
First purely organic phosphor Scientists in the US have made a major advance in the development of novel light-emitting materials by designing the first purely organic phosphorescent compound. mark for My Articles similar articles
Chemistry World
July 2, 2014
Victoria Richards
Molecular brass Brass has been known to man since prehistoric times; now scientists in Germany have isolated the first molecular example of the copper -- zinc alloy. mark for My Articles similar articles
Technology Research News
January 15, 2003
Eric Smalley
Metal stores more hydrogen One reason the world isn't running on hydrogen fuel is that it's hard to store. Researchers from the National University of Singapore have made an accidental discovery that brings the promise of clean hydrogen energy a big step forward. mark for My Articles similar articles
Chemistry World
May 8, 2015
Jennifer Newton
Chemists snare 17-electron half-sandwich radical A team from Nanjing University in China has successfully synthesized and characterized the organometallic radical cation [(C 6Me 6)Cr(CO) 3] +. mark for My Articles similar articles
Chemistry World
December 19, 2010
Simon Hadlington
Novel route to key aromatics US chemists have found a new way to create aromatic compounds from straight chains of hydrocarbons by using an iridium-based catalyst. mark for My Articles similar articles