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Chemistry World
October 5, 2006
Mark Peplow
Boron Shows Its Negative Side A molecule that hosts a negatively-charged boron atom could prove to be an exciting addition to the chemist's toolbox, according to researchers who have isolated the anion as its lithium salt. mark for My Articles similar articles
Chemistry World
February 6, 2012
David Bradley
10 out of 10 for boron's coordinated effort A team in the US has created a boron compound that has the highest coordination number of any planar species, squeezing 10 spoke-like bonds from a central metal hub to 10 boron atoms equally spaced around a nanoscopic wheel. mark for My Articles similar articles
Reactive Reports
Issue 54
David Bradley
Metals Take on Carbon's Bonding Characteristics A rethink about chemical bonding might be in the cards thanks to research that shows that the metal indium forms bonds in a manner not dissimilar to organic carbon atoms. mark for My Articles similar articles
Chemistry World
March 3, 2010
Jon Cartwright
Hydrocarbon turns superconductor Researchers in Japan have created the first superconducting material based on a molecule of carbon and hydrogen atoms. mark for My Articles similar articles
Chemistry World
December 23, 2008
Tom Westgate
Gallium and uranium join forces A molecule featuring the first ever uranium-gallium bond may shed light on how related carbene ligands selectively extract uranium from lanthanides mark for My Articles similar articles
Chemistry World
May 30, 2012
Jon Cartwright
Tiny buckyball grown around metal atom An international team of researchers has observed the smallest fullerene to form spontaneously to date using metal atoms for stabilization. mark for My Articles similar articles
Chemistry World
August 14, 2012
Andy Extance
Carbon clusters score lucky seven US and Chinese chemists say that they've calculated the structure of a stable carbon dication that would have a higher coordination number than any yet seen experimentally. mark for My Articles similar articles
Chemistry World
December 7, 2009
Simon Hadlington
Metal atoms in carbon nanotubes caught on film An international team of researchers has filmed individual metal atoms as they move around and react within the confines of a carbon nanotube. mark for My Articles similar articles
Chemistry World
January 15, 2010
Kate McAlpine
Capturing carbon with copper A team of researchers in the Netherlands have devised a trap that can pull carbon dioxide out of the air. mark for My Articles similar articles
Chemistry World
April 15, 2010
Simon Hadlington
Lead joins the aromatic ring club Scientists in Japan have successfully incorporated an atom of lead into an aromatic molecule - the heaviest metal so far to be 'aromatised'. mark for My Articles similar articles
Chemistry World
June 5, 2006
Simon Hadlington
The Attraction of Gold for Gold Researchers are unravelling some of the fundamental chemistry surrounding a key but poorly understood aspect of the coordination chemistry of gold -- the weak `aurophilic' interactions between adjacent atoms of Au(I) in organic complexes. mark for My Articles similar articles
Reactive Reports
David Bradley
Subjective Suboxide Carbon monoxide and carbon dioxide are probably the best known molecules containing just carbon and oxygen, but they do form others, such as carbon suboxide (C3O2), which is one of the most stable. mark for My Articles similar articles
Technology Research News
June 2, 2004
Buckyballs Gain Smaller Kin Researchers from Xiamen University and the Chinese Academy of Sciences have constructed a smaller version of the buckyball or C60 fullerene molecule, a spherical cage of carbon atoms. mark for My Articles similar articles
Chemistry World
April 29, 2009
Matt Wilkinson
World's first 'naked' uranium-transition metal bond formed UK scientists have made 'naked' uranium-transition metal bonds, providing vital evidence that valence orbitals can play a role in actinide bonding. mark for My Articles similar articles
Chemistry World
January 24, 2010
Andy Extance
Boron cluster forms unique ring system Clusters of nineteen boron atoms gather together in a ring structure unlike any other seen, with two planar -bonded aromatic systems nestled inside one another. mark for My Articles similar articles
Chemistry World
August 1, 2010
Mike Brown
Snapshots of mystery molecular structures Researchers have used atomic force microscopy to produce clear molecular images that can help determine the correct atomic structure of unknown organic molecules. mark for My Articles similar articles
Chemistry World
February 21, 2007
Tom Westgate
Complex Organic Molecules Teamed with Iodine Chemists have developed a method for constructing complex halogen-containing organic molecules from simple compounds in a single step. The discovery could pave the way for the synthesis of many potentially useful naturally occurring molecules. mark for My Articles similar articles
Chemistry World
May 9, 2010
Hayley Birch
Filming fullerene formation Real-time, atomic level microscopy has revealed that the round, cage-like structures of fullerenes can form directly from sheets containing large numbers of carbon atoms. mark for My Articles similar articles
Technology Research News
August 13, 2003
Carbon wires expand nano toolkit Scientists looking for building blocks to form electronics and machines that are not much bigger than molecules have gained a new tool. mark for My Articles similar articles
Chemistry World
September 19, 2010
Simon Hadlington
One dimensional carbon chains get longer Researchers in Canada have synthesised the longest polyyne to date - a linear chain of carbon atoms. mark for My Articles similar articles
Chemistry World
October 29, 2009
Phillip Broadwith
Two metals are better than one UK chemists have developed reagents that can metallate ethers and ethene at room temperature without them disintegrating. mark for My Articles similar articles
Technology Research News
December 29, 2004
Coated Nanotubes Make Biosensors Researchers are using carbon nanotubes to sense single molecules, and are tapping the way carbon nanotubes give off near-infrared light in order to read what the sensors have detected. mark for My Articles similar articles
Reactive Reports
Issue 63
David Bradley
Natural Copy Cat While plants convert carbon dioxide into sugar and oxygen, chemists are having a more difficult time finding an efficient method for converting carbon dioxide into useful fuels. mark for My Articles similar articles
Chemistry World
November 8, 2007
James Mitchell Crow
First Mg(I) Complex Made Chemists have created the first stable magnesium(I) compounds, a breakthrough for a metal whose chemistry is ruled by the oxidation state. mark for My Articles similar articles
Chemistry World
December 15, 2010
Hayley Birch
New technique probes electron properties of individual atoms A new, low voltage electron microscopy technique allows scientists to discriminate not just between atoms of different elements but between atoms of the same element in different electronic states. mark for My Articles similar articles
Chemistry World
March 10, 2006
Dual Organometallics Enhance Zinc Reactivity Chemists have synthesised organometallic compounds that enable zinc to participate in directed metalation of organic substrates. mark for My Articles similar articles
Chemistry World
June 14, 2012
David Bradley
Tripling up on boron bonds Carbon and nitrogen are well known for their triple bonds, but making stable compounds with a triple bond between two boron atoms hadn't been achieved despite the computational possibilities. Until now. mark for My Articles similar articles
Technology Research News
October 8, 2003
Nanotubes harvest electrons Researchers from the University of Bologna and the University of Trieste in Italy, and the University of Notre Dame have found a way to alter carbon nanotubes so that they efficiently separate electrical charge. The method could lead to more efficient solar cells. mark for My Articles similar articles
Chemistry World
May 16, 2006
Jon Evans
Buckyballs Worth Their Weight in Gold A team of chemists and physicists has uncovered evidence for the existence of hollow buckyball-like cages made of gold. mark for My Articles similar articles
Chemistry World
December 10, 2008
Simon Hadlington
Alcohol enantiomer conundrum cracked UK chemists have discovered a straightforward new way to make chiral tertiary alcohols that gives selective access to either enantiomer. mark for My Articles similar articles
Chemistry World
May 13, 2013
Philip Ball
The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded? mark for My Articles similar articles
Technology Research News
March 9, 2005
Nanotubes Boost Molecular Devices Researchers have constructed an extremely small transistor from a pair of single-walled carbon nanotubes and organic molecules. The tiny transistor could eventually be used in ultra-low-power electronics. mark for My Articles similar articles
Chemistry World
November 7, 2013
Polly Wilson
Hydrogen adopts alkali metal position For the first time, scientists have shown that hydrogen can stand in for alkali metals in typical alkali metal structures. mark for My Articles similar articles
Chemistry World
January 20, 2010
James Urquhart
Disilicate synthesis success A compound containing a stable silicon-silicon bond between two negatively charged pentacoordinated silicon atoms - silicates - has been synthesized and isolated for the first time by Japanese researchers. mark for My Articles similar articles
Chemistry World
February 27, 2014
Simon Hadlington
Quantum tunnelling sparks chemistry on cold surfaces Chemistry in deep space could be more diverse than thought after the discovery that larger atoms can quantum tunnel. mark for My Articles similar articles
Chemistry World
June 23, 2011
Simon Hadlington
Breaking the carbon-fluorine bond US chemists have discovered a new way to break the bond between carbon and fluorine atoms - the strongest carbon bond there is. mark for My Articles similar articles
Chemistry World
May 22, 2008
Richard Van Noorden
Xenon doubled up with water Creating a water molecule with two noble gas atoms interpolated into its structure sounds an improbable feat, but a international team of researchers now claim to have trapped just such an exotic compound in xenon. mark for My Articles similar articles
Chemistry World
October 4, 2007
Richard Van Noorden
Nanofibers Show Hydrogen Promise UK chemists have overcome the shortcomings of a promising hydrogen storage material by simply converting it into nanofibers. mark for My Articles similar articles
Chemistry World
March 2011
Column: The crucible Chemistry cannot all be reduced to physics, argues Philip Ball mark for My Articles similar articles
Chemistry World
September 6, 2013
Melissae Fellet
Unravelling stereochemistry via mass spectrometry Researchers have used mass spectrometry to determine the stereochemistry of a prototypical chiral molecule, CHBrClF. mark for My Articles similar articles
Chemistry World
December 18, 2012
Caryl Richards
Boron vapor trail leads to heterofullerenes A team of scientists has developed a simple way to synthesize heterofullerenes -- fullerenes with atoms other than carbon in their structure -- by exposing fullerene to boron vapor during their growth. mark for My Articles similar articles
Chemistry World
September 6, 2007
Tom Westgate
Probe Maps Individual Atoms in Semiconductor Troublesome clusters of dopant atoms have been 'seen' for the first time. Researchers have drawn up the first 3D maps of the individual atoms in a semiconductor. mark for My Articles similar articles
Chemistry World
May 28, 2012
Hayley Birch
Buckyballs grow by gobbling up carbon New insights into the formation of some of chemistry's most iconic molecules - the fullerenes - suggest they grow by 'eating' carbon atoms. mark for My Articles similar articles
Technology Research News
June 4, 2003
Study shows DNA will fill tubes Researchers from the Max Planck Institute in Germany have shown by computer simulation that it is possible to insert DNA into a carbon nanotube. mark for My Articles similar articles
Chemistry World
June 25, 2012
Michael Gross
Running Rings Around Molecular Wires New research could open up the possibility of using new carbon compounds as wires in molecular electronics. mark for My Articles similar articles
Chemistry World
November 29, 2010
Simon Hadlington
Mystery of diamond polishing solved? Mike Ashfold, an expert on the chemistry of diamond at the University of Bristol in the UK, says, 'Polishers have long recognised that some diamond surfaces polish more easily, and more successfully, than others. mark for My Articles similar articles
Wired
Erin Biba
Molecular Frameworks, the Building Blocks of All Life The world is complicated, but not as complicated as you might think. Most organic molecules derive from a few relatively simple architectures. mark for My Articles similar articles
Chemistry World
May 27, 2014
Simon Hadlington
Unusual H-bond patterns revealed in single molecule image Researchers in the US have used a scanning tunnelling microscope to produce the latest images of structure and bonding in a single molecule, by sensing the molecule's local potential energy landscape. mark for My Articles similar articles
Technology Research News
February 25, 2004
Nanotube mix makes liquid crystal Carbon nanotubes are rolled-up sheets of carbon atoms that can be as narrow as 0.4 nanometers, or the span of four hydrogen atoms. They have useful electrical and mechanical properties and are a leading player in nanotechnology. mark for My Articles similar articles
Chemistry World
October 18, 2007
Simon Hadlington
Nanoparticle Reveals Sulfur's Midas Touch Researchers in the US have taken a snapshot of the inside of a gold nanoparticle, shedding crucial new light on one of chemistry's longest-standing questions: how does sulfur bind to gold? mark for My Articles similar articles