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Chemistry World
January 10, 2014
Jennifer Newton
Nitrenium hugs stabilize positively rare complexes Everyone knows that like charges repel one another. But unusual coordination compounds bearing cationic ligands bound to cationic metals have been prepared by scientists in Israel, opening up fresh opportunities for organic transformations. mark for My Articles similar articles
Chemistry World
January 27, 2010
Phillip Broadwith
Cracking carbon-carbon bonds Chemists in the US have discovered a tungsten complex that can break a strong carbon-carbon bond in an aromatic ring. mark for My Articles similar articles
Chemistry World
February 9, 2012
Simon Hadlington
Molecule mimics molybdenum catalyst Chemists in the US have created a molecule that closely resembles the key active portion of molybdenum disulfide, an important solid industrial catalyst that shows promise for the generation of hydrogen from water. mark for My Articles similar articles
Chemistry World
October 28, 2013
Jennifer Newton
Crystal within a crystal Colleagues at the University of Strasbourg used a molecular tectonics strategy to prepare the crystals. mark for My Articles similar articles
Chemistry World
October 22, 2009
Simon Hadlington
Carbenes catalyse metal-metal bonds in organometallics Chemists in the US have discovered a novel way to transform organometallic compounds so that new metal-metal bonds are created. mark for My Articles similar articles
Chemistry World
April 28, 2014
Hamish Crawford
Crystal structures unpacked A researcher in the UK has shed new light on which interactions are important in the packing of crystal structures. mark for My Articles similar articles
Chemistry World
November 28, 2013
Andy Extance
Base metal catalysts strike hydrogenation gold Three teams have shown that chemists need not rely only on expensive and toxic precious metal catalysts for hydrogenation -- they've found complementary alternatives based on cheap, abundant and safer transition metals. mark for My Articles similar articles
Chemistry World
March 10, 2006
Dual Organometallics Enhance Zinc Reactivity Chemists have synthesised organometallic compounds that enable zinc to participate in directed metalation of organic substrates. mark for My Articles similar articles
Chemistry World
August 5, 2010
Simon Hadlington
Nitrogenase found to be a two-trick pony An enzyme whose job is to convert nitrogen gas to ammonia - a process known as nitrogen fixation - can also reduce carbon monoxide US researchers have discovered. mark for My Articles similar articles
Chemistry World
May 28, 2008
Lewis Brindley
Changing the face of a water splitting catalyst Australian chemists have grown crystals of the water-splitting catalyst titanium dioxide that are many times more reactive than usual. mark for My Articles similar articles
Chemistry World
September 4, 2013
Mark Peplow
Iron catalyst offers nitrogenase clues It is one of the most enduring mysteries in chemistry: how do certain bacteria fix nitrogen from the air? mark for My Articles similar articles
Chemistry World
November 2, 2011
Phillip Broadwith
Do Carbyne Radicals Really Exist in Aqueous Solution? Carbyne radicals are ejected from molybdenum clusters in water and react together to make lots of organic molecules, including alkynes mark for My Articles similar articles
Chemistry World
March 27, 2014
Simon Hadlington
Popcorn-like explosion of single crystals explained Chemists have created single crystals of metal coordination complexes that explode violently when exposed to UV light, leaping high into the air. mark for My Articles similar articles
Chemistry World
June 5, 2006
Simon Hadlington
The Attraction of Gold for Gold Researchers are unravelling some of the fundamental chemistry surrounding a key but poorly understood aspect of the coordination chemistry of gold -- the weak `aurophilic' interactions between adjacent atoms of Au(I) in organic complexes. mark for My Articles similar articles
Chemistry World
July 25, 2014
Polly Wilson
Uranium complexes unlock feedstock potential of carbon dioxide European scientists have synthesized uranium complexes that take them a step closer to producing commodity chemicals from carbon dioxide. mark for My Articles similar articles
Chemistry World
March 19, 2012
James Mitchell Crow
Nickel plays host to quickie xylene separation An efficient new way to separate isomers of xylene, a chemical feedstock derived from crude oil, could slash the time and energy required to purify this key intermediate. mark for My Articles similar articles
Chemistry World
June 2, 2010
Lewis Brindley
Reactions in a crystal Crystals that can alter their composition without changing the structure of their solid lattice have been developed by US researchers. mark for My Articles similar articles
Chemistry World
March 25, 2012
Phillip Broadwith
Germanium-Oxygen Double Bond Takes Centre Stage The first compound with a germanium-oxygen double bond has been created by Japanese scientists. mark for My Articles similar articles
Chemistry World
July 12, 2007
Tom Westgate
Model Enzyme Attacks Alkyl Mercury US chemists have devised a molecular mimic for an enzyme that destroys toxic alkyl mercury pollutants. mark for My Articles similar articles
Chemistry World
August 21, 2008
Fred Campbell
Double bonding with silicon In a landmark for silicon chemistry, US researchers have reported the first stable silicon (0) compound to contain a silicon-silicon double bond. mark for My Articles similar articles
Chemistry World
June 1, 2006
Michael Gross
New Twists on Catalysis Chemists around the world have discovered several new twists to improve the performance of asymmetric catalysts in hydrogenation reactions. mark for My Articles similar articles
Chemistry World
January 30, 2009
Hayley Birch
Nanocrystals Get in Shape for Catalysis New research in fine tuning the shape and size of nanoparticles could lead to important advances in catalysis. mark for My Articles similar articles
Chemistry World
August 14, 2012
Andy Extance
Carbon clusters score lucky seven US and Chinese chemists say that they've calculated the structure of a stable carbon dication that would have a higher coordination number than any yet seen experimentally. mark for My Articles similar articles
Chemistry World
September 18, 2012
Phillip Broadwith
Caffeine crystals with an elastic bent Indian chemists have discovered a highly elastic but crystalline material made from caffeine. The crystals maintain their elasticity down to -100 C. mark for My Articles similar articles
Chemistry World
May 8, 2015
Jennifer Newton
Chemists snare 17-electron half-sandwich radical A team from Nanjing University in China has successfully synthesized and characterized the organometallic radical cation [(C 6Me 6)Cr(CO) 3] +. mark for My Articles similar articles
Chemistry World
June 11, 2009
Lewis Brindley
'Electronic glue' makes nanocrystals connect American chemists have developed an 'electronic glue' to link nanocrystals together - allowing groups of the crystals to be highly conductive. mark for My Articles similar articles
Chemistry World
September 30, 2011
Colourful Research Jeremy Smith talks about why choosing inorganic chemistry was a case of columns versus color. mark for My Articles similar articles
Chemistry World
August 28, 2015
Simon Higgins
D-block chemistry Mark Winter's D-block chemistry, originally published as part of the Oxford chemistry primer series in 1995, and now revised and updated, is a good and approachable introduction to put this bewilderment in context. mark for My Articles similar articles
Chemistry World
May 3, 2007
Simon Hadlington
The Many Faces of Platinum Researchers in the U.S. and China have discovered a way to grow multi-faceted nanocrystals of platinum that have much higher catalytic activity than the conventional crystalline forms of the metal. mark for My Articles similar articles