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Chemistry World
October 11, 2013
Andy Extance
'Tetrel bonding' emerges from I -hole Researchers have coined the term 'tetrel bonding' to highlight little-studied but powerful non-covalent bonding between electron donors and the group 14 elements, silicon, germanium and tin. mark for My Articles similar articles
Chemistry World
May 29, 2015
Andy Extance
Noble gas joins I -hole interaction crowd Despite noble gases' characteristic unreactivity, Spanish chemists have calculated that molecules containing xenon can interact non-covalently through what they've called 'aerogen bonding'. mark for My Articles similar articles
Chemistry World
October 3, 2014
Jennifer Newton
Assessing covalency in the hydrogen bond zoo Worried that the concept of hydrogen bonding has been getting fuzzier over time, scientists in Germany have sought a fresh look at the very nature of these bonds, and how much covalency they involve. mark for My Articles similar articles
Chemistry World
January 29, 2015
Santiago Alvarez
What we mean when we talk about bonds The chemical bond is still a matter of lively debate among chemists, even a century after Gilbert Lewis introduced his electron pair bonding concept. mark for My Articles similar articles
Chemistry World
February 18, 2011
Carol Stanier
Speed dating for pharmaceuticals A simple analysis of hydrogen bond strengths finds the best crystallisation partners for drugs, say UK scientists. mark for My Articles similar articles
Chemistry World
November 3, 2010
Andy Extance
Hydrogen bond set to be redefined The world authority on chemical nomenclature is preparing to scrap the familiar hydrogen bond definition, in light of recent evidence about its true nature. mark for My Articles similar articles
Chemistry World
March 25, 2013
David Bradley
Hydrogen bond under the microscope Scientists in Japan have designed a scanning tunnelling microscope tip that allowed them to measure electron transfer across a single hydrogen bond. mark for My Articles similar articles
Chemistry World
December 4, 2006
Richard Van Noorden
Hydrogen Gets Promiscuous Hydrogen is a more promiscuous element than chemists have appreciated: it can form up to six strong chemical bonds in some solids, researchers report. mark for My Articles similar articles
Chemistry World
March 24, 2009
Karen Harries-Rees
Alkali metals reveal a taste for clam Researchers have discovered a chemical curiosity, alkali metals that prefer aromatic surfaces to water and form clam-like structures. mark for My Articles similar articles
Chemistry World
December 10, 2014
Jason Woolford
I meets I for a hole lot of bonding Researchers in India have provided experimental verification that a co-operative I -hole and I -hole are responsible for holding the molecules of an isothiocyanate based peptide together in its crystal lattice. mark for My Articles similar articles
Chemistry World
November 10, 2014
Andy Extance
Hydrogen bond pictures come under close scrutiny Scientists have cast doubt on whether striking atomic force microscopy images previously thought to show hydrogen bonds are real or merely an artefact. mark for My Articles similar articles
Chemistry World
June 14, 2012
David Bradley
Tripling up on boron bonds Carbon and nitrogen are well known for their triple bonds, but making stable compounds with a triple bond between two boron atoms hadn't been achieved despite the computational possibilities. Until now. mark for My Articles similar articles
Chemistry World
August 21, 2008
Fred Campbell
Double bonding with silicon In a landmark for silicon chemistry, US researchers have reported the first stable silicon (0) compound to contain a silicon-silicon double bond. mark for My Articles similar articles
Chemistry World
May 13, 2013
Philip Ball
The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded? mark for My Articles similar articles
Chemistry World
September 14, 2011
Laura Howes
Aspirin Still Has Some Secrets Left to Give up The overlooked stereoelectric effect in aspirin makes the molecule less polar, which may improve the drug's bioavailability. mark for My Articles similar articles
Technology Research News
August 13, 2003
Carbon wires expand nano toolkit Scientists looking for building blocks to form electronics and machines that are not much bigger than molecules have gained a new tool. mark for My Articles similar articles
Chemistry World
May 21, 2010
Simon Hadlington
H-bond partner-swapping seen in the flesh The dance moves that a water molecule makes as it flips hydrogen bonds from one partner to another have been captured by US researchers. mark for My Articles similar articles
Chemistry World
September 26, 2013
Akshat Rathi
First pictures of hydrogen bonds unveiled Researchers in China report the first visualization of a hydrogen bond using atomic force microscopy. mark for My Articles similar articles
Technology Research News
November 17, 2004
Low-Pressure Material Holds Hydrogen One key to using hydrogen as a fuel is finding practical ways to store it. Researchers have discovered a kinetic trapping effect that allows hydrogen to be adsorbed. mark for My Articles similar articles
Chemistry World
March 27, 2012
Erica Wise
Unlocking the mysteries of ice The unusual properties of ice under compression are due to Coulomb repulsion between bonding and non-bonding electron pairs, say scientists from Singapore and China. mark for My Articles similar articles
Chemistry World
September 3, 2008
Lewis Brindley
Hydroxide argument settled Scientists in Germany say they have settled an argument over how hydroxide ions travel quite so quickly through water, after finding evidence that they can donate a weak hydrogen bond. mark for My Articles similar articles
Chemistry World
April 11, 2010
Simon Hadlington
Phosphorus fragments trapped Researchers in the US and Germany have shown how a rare and highly reactive form of phosphorus can be captured and crystallised, making it stable even at room temperature. mark for My Articles similar articles
Chemistry World
March 2011
Column: The crucible Chemistry cannot all be reduced to physics, argues Philip Ball mark for My Articles similar articles
Chemistry World
December 15, 2010
Hayley Birch
New technique probes electron properties of individual atoms A new, low voltage electron microscopy technique allows scientists to discriminate not just between atoms of different elements but between atoms of the same element in different electronic states. mark for My Articles similar articles
Chemistry World
January 20, 2010
James Urquhart
Disilicate synthesis success A compound containing a stable silicon-silicon bond between two negatively charged pentacoordinated silicon atoms - silicates - has been synthesized and isolated for the first time by Japanese researchers. mark for My Articles similar articles
Chemistry World
May 8, 2013
Cara E Sutton
Coming unstuck with DNA A DNA-based glue has been developed by scientists at the University of Illinois, US. The adhesive uses DNA base pair mimics that bind to each other more strongly than their natural counterparts and may lead to glues far more powerful than Super Glue. mark for My Articles similar articles
Chemistry World
November 3, 2015
Matthew Gunther
IR spectroscopy stretches knowledge of hydrogen bonding Scientists in Denmark have, for the first time, detected a hydrogen bond between an N -- H and phosphorus in the gas phase. mark for My Articles similar articles
Chemistry World
September 4, 2015
Hugh Cowley
Hypervalent bonding controversy out for the electron count? A researcher in the UK has presented a controversial new definition for hypervalency that may ignite debates over atomic charge and allow students to draw nitrogen atoms with five covalent bonds. mark for My Articles similar articles
Chemistry World
February 12, 2013
Philip Ball
Water structure controversy laid to rest? A controversy about the structure of liquid water that has raged for almost a decade may be laid to rest by a new computational study. mark for My Articles similar articles
Chemistry World
November 7, 2013
Polly Wilson
Hydrogen adopts alkali metal position For the first time, scientists have shown that hydrogen can stand in for alkali metals in typical alkali metal structures. mark for My Articles similar articles
Chemistry World
May 16, 2010
Simon Hadlington
Anions enjoy a taste of pi European researchers have captured the moment when an anion interacts with the pi electron cloud of an aromatic molecule, something that has been known to occur but never seen at work. mark for My Articles similar articles
Chemistry World
January 28, 2009
Phillip Broadwith
Water spilt with aluminium Aluminium clusters' ability to split water molecules and release hydrogen is dictated by the geometric arrangement of active sites on their surface, US scientists have discovered. mark for My Articles similar articles
Chemistry World
April 28, 2014
Hamish Crawford
Crystal structures unpacked A researcher in the UK has shed new light on which interactions are important in the packing of crystal structures. mark for My Articles similar articles
Chemistry World
October 10, 2014
Laura Fisher
Dangling bonds induce ferromagnetism in graphitic carbon nitride Researchers have achieved ferromagnetism in graphitic carbon nitride, g-C 3N 4, by introducing hydrogen dangling bonds into its two-dimensional structure, making the material suitable for spintronic devices. mark for My Articles similar articles
Reactive Reports
Issue 54
David Bradley
Metals Take on Carbon's Bonding Characteristics A rethink about chemical bonding might be in the cards thanks to research that shows that the metal indium forms bonds in a manner not dissimilar to organic carbon atoms. mark for My Articles similar articles
Reactive Reports
Issue 31
David Bradley
Ammonia for the primordial brew A newly discovered nitrogen-fixation reaction may have played a role in the emergence of life, according to German researchers. mark for My Articles similar articles
Chemistry World
July 16, 2009
Simon Hadlington
Strange vibrations Researchers in Taiwan have shown that in a relatively simple molecular system the induced vibrations can inhibit the breaking of the bond and slow the reaction down. mark for My Articles similar articles
Chemistry World
November 5, 2007
Ned Stafford
Joining up Nanocircuits A team of scientists have covalently bonded strings of porphyrin molecules on a gold surface -- a step forward in the quest to develop nano-electronics. mark for My Articles similar articles
Chemistry World
June 5, 2006
Simon Hadlington
The Attraction of Gold for Gold Researchers are unravelling some of the fundamental chemistry surrounding a key but poorly understood aspect of the coordination chemistry of gold -- the weak `aurophilic' interactions between adjacent atoms of Au(I) in organic complexes. mark for My Articles similar articles
Chemistry World
May 27, 2014
Simon Hadlington
Unusual H-bond patterns revealed in single molecule image Researchers in the US have used a scanning tunnelling microscope to produce the latest images of structure and bonding in a single molecule, by sensing the molecule's local potential energy landscape. mark for My Articles similar articles
Technology Research News
December 15, 2004
Kimberly Patch
Molecule Harvests Water's Hydrogen The key to producing clean hydrogen energy is finding a non-polluting method to extract pure hydrogen from its most abundant source, water. Researchers have developed a supramolecular complex that could be used in devices that use light energy to extract hydrogen from water. mark for My Articles similar articles
Technology Research News
September 24, 2003
Artificial DNA stacks metal atoms In recent years, researchers have replaced some of DNA's natural bases with those that attach to metal atoms in order to coax DNA to organize metal ions into tiny structures. Researchers in Japan have tapped the method to form stacks of single metal ions. mark for My Articles similar articles
Chemistry World
June 9, 2009
Simon Hadlington
Super sponges soak up gas Researchers in the US have shown that a recently discovered class of compound based on light elements can store gas at least as efficiently as the most promising metal organic framework candidates. mark for My Articles similar articles
Chemistry World
November 22, 2009
Lewis Brindley
Bonding under pressure An unusual compound of xenon and hydrogen has been made under high pressure by researchers in the US. mark for My Articles similar articles
Chemistry World
February 28, 2008
James Mitchell Crow
Chloride Ions in a Bind Chemists in the US have designed a donut-shaped molecule that tightly binds negatively-charged chloride ions. mark for My Articles similar articles
Technology Research News
June 4, 2003
Study shows DNA will fill tubes Researchers from the Max Planck Institute in Germany have shown by computer simulation that it is possible to insert DNA into a carbon nanotube. mark for My Articles similar articles
Chemistry World
January 8, 2014
Philip Ball
We choose to go to the muon Chemists Mohammad Goli and Shant Shahbazian posit two new light elements. They are muonium (Mu), in which an electron orbits a positively charged muon ( +), and muonic helium (He ), in which an electron orbits a 'nucleus' consisting of an alpha particle and a negative muon. mark for My Articles similar articles
Chemistry World
April 29, 2009
Matt Wilkinson
World's first 'naked' uranium-transition metal bond formed UK scientists have made 'naked' uranium-transition metal bonds, providing vital evidence that valence orbitals can play a role in actinide bonding. mark for My Articles similar articles
Chemistry World
June 23, 2011
Simon Hadlington
Breaking the carbon-fluorine bond US chemists have discovered a new way to break the bond between carbon and fluorine atoms - the strongest carbon bond there is. mark for My Articles similar articles
Chemistry World
June 25, 2014
Tim Wogan
Unusual 2D silica allotrope predicted A graphene-like allotrope of silica with unusual physical and electrical properties has been predicted by theoretical chemists in Turkey. mark for My Articles similar articles