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Chemistry World September 26, 2013 Akshat Rathi |
First pictures of hydrogen bonds unveiled Researchers in China report the first visualization of a hydrogen bond using atomic force microscopy. |
Chemistry World May 21, 2010 Simon Hadlington |
H-bond partner-swapping seen in the flesh The dance moves that a water molecule makes as it flips hydrogen bonds from one partner to another have been captured by US researchers. |
Chemistry World October 3, 2014 Jennifer Newton |
Assessing covalency in the hydrogen bond zoo Worried that the concept of hydrogen bonding has been getting fuzzier over time, scientists in Germany have sought a fresh look at the very nature of these bonds, and how much covalency they involve. |
Chemistry World September 13, 2012 Philip Ball |
Bright idea to probe bond order The order of multiple bonds can be uncovered using atomic force microscopy, according to Leo Gross of IBM Research in Zurich and his co-workers. |
Chemistry World November 3, 2010 Andy Extance |
Hydrogen bond set to be redefined The world authority on chemical nomenclature is preparing to scrap the familiar hydrogen bond definition, in light of recent evidence about its true nature. |
Chemistry World May 27, 2014 Simon Hadlington |
Unusual H-bond patterns revealed in single molecule image Researchers in the US have used a scanning tunnelling microscope to produce the latest images of structure and bonding in a single molecule, by sensing the molecule's local potential energy landscape. |
Chemistry World February 18, 2011 Carol Stanier |
Speed dating for pharmaceuticals A simple analysis of hydrogen bond strengths finds the best crystallisation partners for drugs, say UK scientists. |
Chemistry World November 10, 2014 Andy Extance |
Hydrogen bond pictures come under close scrutiny Scientists have cast doubt on whether striking atomic force microscopy images previously thought to show hydrogen bonds are real or merely an artefact. |
Chemistry World March 25, 2013 David Bradley |
Hydrogen bond under the microscope Scientists in Japan have designed a scanning tunnelling microscope tip that allowed them to measure electron transfer across a single hydrogen bond. |
Chemistry World September 3, 2008 Lewis Brindley |
Hydroxide argument settled Scientists in Germany say they have settled an argument over how hydroxide ions travel quite so quickly through water, after finding evidence that they can donate a weak hydrogen bond. |
Chemistry World January 29, 2015 Santiago Alvarez |
What we mean when we talk about bonds The chemical bond is still a matter of lively debate among chemists, even a century after Gilbert Lewis introduced his electron pair bonding concept. |
Chemistry World January 2, 2014 Ian Randall |
Picosecond 'kettle' to probe chemical reactions A way to boil water in less than a trillionth of a second has been devised by researchers. The approach, which is still theoretical, uses a concentrated pulse of terahertz radiation to raise the temperature of a small sample of water by around 600 C. |
Chemistry World April 26, 2011 Manisha Lalloo |
Pnicogens link up as new bond is discovered German researchers have discovered a chemical oddity - a new type of intramolecular interaction between group 15 atoms, which is as strong as a hydrogen bond. These interactions could be used to build supramolecular structures. |
Chemistry World March 9, 2006 Katharine Sanderson |
Covalent Bonds Crack Under the Strain Chemists must consider engineering principles when designing molecules following news that tough carbon-to-carbon bonds break easily under mechanical strain. |
Chemistry World March 27, 2012 Erica Wise |
Unlocking the mysteries of ice The unusual properties of ice under compression are due to Coulomb repulsion between bonding and non-bonding electron pairs, say scientists from Singapore and China. |
Reactive Reports Issue 72 David Bradley |
Ice Age the Movie The ordered structure of ice dissolves little by little into disorder when a tiny burst of light hits an ice crystal. |
Chemistry World June 13, 2012 Simon Hadlington |
Exploding molecule provides 3D bond images Researchers from the US and Germany have demonstrated a new way to obtain accurate three-dimensional images of molecules, with precise measurements of the geometry of the molecule's chemical bonds. |
Chemistry World January 29, 2012 Andy Extance |
Calculations reveal carbon-carbon quadruple bond C 2's two carbon atoms aren't joined by a double bond as usually thought, or even a triple bond, but in fact a quadruple bond. |
Chemistry World August 13, 2010 James Urquhart |
Zooming in on intermolecular bonds German researchers have captured clear images of intermolecular bonds for the first time using a modified form of scanning tunnelling microscopy. |
Chemistry World June 14, 2013 Philip Ball |
Protons wander freely in icy gas giant cores If you squeeze ice hard enough, its protons fall off. That's the conclusion of a new study by Malcolm Guthrie of the Carnegie Institution of Washington and colleagues. |
Chemistry World July 13, 2015 Philip Ball |
First snapshot of elusive intermediate supplies surprise A team near Zurich in Switzerland, has been able to take a single-molecule snapshot of an intermediate in a common class of organic reactions. |
Chemistry World March 2011 |
Column: The crucible Chemistry cannot all be reduced to physics, argues Philip Ball |
Chemistry World May 13, 2013 Philip Ball |
The name's (quadruple) bond? The nature of C 2 is still imperfectly understood and has recently sparked extensive debate in the chemical literature. The question seems simple: how are the two atoms bonded? |
Chemistry World May 29, 2015 Andy Extance |
Noble gas joins I -hole interaction crowd Despite noble gases' characteristic unreactivity, Spanish chemists have calculated that molecules containing xenon can interact non-covalently through what they've called 'aerogen bonding'. |
Chemistry World April 2, 2012 Jon Cartwright |
Hydrogen That Mimics Graphene Researchers claim to have discovered a new phase of hydrogen in which the diatomic molecules break apart to form six-atom rings, similar to graphene. The new phase, which occurs at very high pressures, could be a stepping stone towards a long-sought after phase: metallic hydrogen. |
Chemistry World November 3, 2015 Matthew Gunther |
IR spectroscopy stretches knowledge of hydrogen bonding Scientists in Denmark have, for the first time, detected a hydrogen bond between an N -- H and phosphorus in the gas phase. |
Chemistry World March 31, 2009 Lewis Brindley |
Giving molecules a stretch A simple way to stretch small molecules and measure the forces at play has been developed by researchers in the US. |
Chemistry World April 29, 2009 Matt Wilkinson |
World's first 'naked' uranium-transition metal bond formed UK scientists have made 'naked' uranium-transition metal bonds, providing vital evidence that valence orbitals can play a role in actinide bonding. |
Chemistry World September 20, 2012 Jon Evans |
World's smallest ice cube created Ice crystals must contain at least 275 water molecules, say German chemists. This size limit has implications for any process that involves ice particles, from cloud formation to making the perfect gin and tonic. |
Chemistry World May 12, 2011 Jon Cartwright |
'Chemical soldering' heralds single molecule electronics Scientists in Japan and Switzerland have demonstrated how to wire up single molecules with conductive nanowires. |
Chemistry World September 12, 2013 Andy Extance |
Sulfur difluoride dimer exposes bonding strangeness Calculations on unusual bonding in the sulfur difluoride dimer FSSF 3 have provided evidence to help explain why some compounds don't follow long-established chemical rules. |
Chemistry World December 9, 2013 Jessica Cocker |
Hydrogen breaks strong bonds with brute force A method developed by Leo Lau of Western University in Canada and colleagues can break C -- H bonds without damaging the rest of the molecule. |
Chemistry World February 13, 2015 Andy Extance |
X-ray laser snaps first bond-forming transition state Using data from x-ray lasers scientists have reconstructed the formation of the carbon monoxide oxidation transition state. |
Chemistry World January 15, 2010 Andy Extance |
Quantum computer hits hydrogen bullseye A basic quantum computer has successfully tackled one of the most challenging tasks facing chemists today - calculating molecular energy from basic scientific principles. |
Chemistry World February 18, 2015 Matthew Gunther |
More bonds probed using x-ray laser Last week we reported that a team of researchers in the US had directly measured a bond transition state and now a separate research group has done the same. |
Chemistry World November 5, 2007 Ned Stafford |
Joining up Nanocircuits A team of scientists have covalently bonded strings of porphyrin molecules on a gold surface -- a step forward in the quest to develop nano-electronics. |
Chemistry World July 22, 2011 Simon Hadlington |
Chemists create a molecular ship in a bottle Chemists have designed a new kind of three-dimensional molecular cage that is held together by a remarkably high number of hydrogen bonds. |
Chemistry World July 29, 2010 Carol Stanier |
Methane all lined up Swiss researchers have found that the way methane molecules vibrate when they hit a nickel surface can have a huge effect on their reactivity. |
Reactive Reports May 2007 David Bradley |
Meeting of Molecular Movie Stars New footage confirms Linus Pauling's theory of chemical bonding proposed half a century ago, and could help explain molecular recognition processes important throughout supramolecular chemistry and molecular biology. |
Chemistry World March 14, 2013 Simon Hadlington |
Elusive desorption precursor spied by x-ray laser Scientists have for the first time directly observed the elusive transient precursor state of a molecule just before it desorbs from a solid surface and enters the gas phase. |
Chemistry World September 29, 2015 |
Navigating chemical space How big is chemistry? I don't mean how important is it, or how many people do it, but rather, how many molecules are there that we could make? |
Reactive Reports Issue 49 David Bradley |
Hydrophobic Water? Researchers have found evidence to indicate that water molecules don't always want to bond to other water molecules, affecting the uniformity of water forming on metal surfaces. |
Chemistry World November 28, 2012 Philip Ball |
Make or break: the laws of motion The machine metaphors of nanochemistry and molecular biology now make it plain that dynamic function arises from the use of weak, temporary interactions. The question biology has to face is: what is the optimal bond strength for a given mechanical function? |
Chemistry World October 11, 2013 Andy Extance |
'Tetrel bonding' emerges from I -hole Researchers have coined the term 'tetrel bonding' to highlight little-studied but powerful non-covalent bonding between electron donors and the group 14 elements, silicon, germanium and tin. |
Reactive Reports December 2006 David Bradley |
Blood, Light, and Water Two molecules that occur naturally in blood have been engineered by scientists to use sunlight to split water into hydrogen and oxygen. |
Chemistry World September 7, 2006 Tom Westgate |
Molecular Framework Sucks up Hydrogen Researchers have now developed a coordination framework material that is the best yet in terms of hydrogen storage. However, the materials currently require low temperatures to achieve the high loading of hydrogen. |
Chemistry World October 13, 2011 Phillip Broadwith |
Following Electrons' Chemical Reaction Quickstep The oscillating electronic states of molecules nearby and passing through a conical intersection can now be probed directly. |
Chemistry World January 28, 2009 Phillip Broadwith |
Water spilt with aluminium Aluminium clusters' ability to split water molecules and release hydrogen is dictated by the geometric arrangement of active sites on their surface, US scientists have discovered. |
Chemistry World March 21, 2007 Richard Van Noorden |
Forcing a Reaction US chemists have forced molecules to react by ripping their bonds apart with ultrasound. The scientists carefully stretched one targeted bond until it snapped, guiding the molecule's subsequent reaction into pathways forbidden by conventional chemistry. |
Chemistry World October 15, 2008 Simon Hadlington |
Long-life light illuminates cells The new dye, based on platinum, will carry on emitting light long after any interfering 'autofluorescence' from naturally occurring molecules in the cell has fizzled out. |